Organic electroluminescent materials and devices

ABSTRACT

Provided are compounds having a first ligand L A  of Formula I 
     
       
         
         
             
             
         
       
     
     Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Applications No. 62/876,874, filed on Jul. 22, 2019, and No.62/833,828, filed on Apr. 15, 2019, the entire contents of which areincorporated herein by reference

FIELD

The present disclosure generally relates to organometallic compounds andformulations and their various uses including as emitters in devicessuch as organic light emitting diodes and related electronic devices.

BACKGROUND

Opto-electronic devices that make use of organic materials are becomingincreasingly desirable for various reasons. Many of the materials usedto make such devices are relatively inexpensive, so organicopto-electronic devices have the potential for cost advantages overinorganic devices. In addition, the inherent properties of organicmaterials, such as their flexibility, may make them well suited forparticular applications such as fabrication on a flexible substrate.Examples of organic opto-electronic devices include organic lightemitting diodes/devices (OLEDs), organic phototransistors, organicphotovoltaic cells, and organic photodetectors. For OLEDs, the organicmaterials may have performance advantages over conventional materials.

OLEDs make use of thin organic films that emit light when voltage isapplied across the device. OLEDs are becoming an increasinglyinteresting technology for use in applications such as flat paneldisplays, illumination, and backlighting.

One application for phosphorescent emissive molecules is a full colordisplay. Industry standards for such a display call for pixels adaptedto emit particular colors, referred to as “saturated” colors. Inparticular, these standards call for saturated red, green, and bluepixels. Alternatively, the OLED can be designed to emit white light. Inconventional liquid crystal displays emission from a white backlight isfiltered using absorption filters to produce red, green and blueemission. The same technique can also be used with OLEDs. The white OLEDcan be either a single emissive layer (EML) device or a stack structure.Color may be measured using CIE coordinates, which are well known to theart.

SUMMARY

In one aspect, the present disclosure provides a compound comprising afirst ligand L_(A) of Formula I

In Formula I: ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; where the first group is selectedfrom the group consisting of:

where the asterisks in each structure indicate adjacent C atoms that areon ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; the ligand L_(A)is complexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.

In another aspect, the present disclosure provides a formulation of thecompounds as described herein.

In yet another aspect, the present disclosure provides an OLED having anorganic layer comprising the compound as described herein.

In yet another aspect, the present disclosure provides a consumerproduct comprising an OLED with an organic layer comprising the compoundas described herein.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does nothave a separate electron transport layer.

DETAILED DESCRIPTION A. Terminology

Unless otherwise specified, the below terms used herein are defined asfollows:

As used herein, the term “organic” includes polymeric materials as wellas small molecule organic materials that may be used to fabricateorganic opto-electronic devices. “Small molecule” refers to any organicmaterial that is not a polymer, and “small molecules” may actually bequite large. Small molecules may include repeat units in somecircumstances. For example, using a long chain alkyl group as asubstituent does not remove a molecule from the “small molecule” class.Small molecules may also be incorporated into polymers, for example as apendent group on a polymer backbone or as a part of the backbone. Smallmolecules may also serve as the core moiety of a dendrimer, whichconsists of a series of chemical shells built on the core moiety. Thecore moiety of a dendrimer may be a fluorescent or phosphorescent smallmolecule emitter. A dendrimer may be a “small molecule,” and it isbelieved that all dendrimers currently used in the field of OLEDs aresmall molecules.

As used herein, “top” means furthest away from the substrate, while“bottom” means closest to the substrate. Where a first layer isdescribed as “disposed over” a second layer, the first layer is disposedfurther away from substrate. There may be other layers between the firstand second layer, unless it is specified that the first layer is “incontact with” the second layer. For example, a cathode may be describedas “disposed over” an anode, even though there are various organiclayers in between.

As used herein, “solution processable” means capable of being dissolved,dispersed, or transported in and/or deposited from a liquid medium,either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed thatthe ligand directly contributes to the photoactive properties of anemissive material. A ligand may be referred to as “ancillary” when it isbelieved that the ligand does not contribute to the photoactiveproperties of an emissive material, although an ancillary ligand mayalter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled inthe art, a first “Highest Occupied Molecular Orbital” (HOMO) or “LowestUnoccupied Molecular Orbital” (LUMO) energy level is “greater than” or“higher than” a second HOMO or LUMO energy level if the first energylevel is closer to the vacuum energy level. Since ionization potentials(IP) are measured as a negative energy relative to a vacuum level, ahigher HOMO energy level corresponds to an IP having a smaller absolutevalue (an IP that is less negative). Similarly, a higher LUMO energylevel corresponds to an electron affinity (EA) having a smaller absolutevalue (an EA that is less negative). On a conventional energy leveldiagram, with the vacuum level at the top, the LUMO energy level of amaterial is higher than the HOMO energy level of the same material. A“higher” HOMO or LUMO energy level appears closer to the top of such adiagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled inthe art, a first work function is “greater than” or “higher than” asecond work function if the first work function has a higher absolutevalue. Because work functions are generally measured as negative numbersrelative to vacuum level, this means that a “higher” work function ismore negative. On a conventional energy level diagram, with the vacuumlevel at the top, a “higher” work function is illustrated as furtheraway from the vacuum level in the downward direction. Thus, thedefinitions of HOMO and LUMO energy levels follow a different conventionthan work functions.

The terms “halo,” “halogen,” and “halide” are used interchangeably andrefer to fluorine, chlorine, bromine, and iodine.

The term “acyl” refers to a substituted carbonyl radical (C(O)—R_(s)).

The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R_(s) or—C(O)—O—R_(s)) radical.

The term “ether” refers to an —OR_(s) radical.

The terms “sulfanyl” or “thio-ether” are used interchangeably and referto a —SR, radical.

The term “sulfinyl” refers to a —S(O)—R_(s) radical.

The term “sulfonyl” refers to a —SO₂—R_(s) radical.

The term “phosphino” refers to a —P(R_(s))₃ radical, wherein each R_(s)can be same or different.

The term “silyl” refers to a —Si(R_(s))₃ radical, wherein each R_(s) canbe same or different.

The term “boryl” refers to a —B(R_(s))₂ radical or its Lewis adduct—B(R_(s))₃ radical, wherein R_(s) can be same or different.

In each of the above, R_(s) can be hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, andcombination thereof. Preferred R_(s) is selected from the groupconsisting of alkyl, cycloalkyl, aryl, heteroaryl, and combinationthereof.

The term “alkyl” refers to and includes both straight and branched chainalkyl radicals. Preferred alkyl groups are those containing from one tofifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl,butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl,2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl,2,2-dimethylpropyl, and the like. Additionally, the alkyl group may beoptionally substituted.

The term “cycloalkyl” refers to and includes monocyclic, polycyclic, andspiro alkyl radicals. Preferred cycloalkyl groups are those containing 3to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl,cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl,adamantyl, and the like. Additionally, the cycloalkyl group may beoptionally substituted.

The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or acycloalkyl radical, respectively, having at least one carbon atomreplaced by a heteroatom. Optionally the at least one heteroatom isselected from O, S, N, P, B, Si and Se, preferably, 0, S or N.Additionally, the heteroalkyl or heterocycloalkyl group may beoptionally substituted.

The term “alkenyl” refers to and includes both straight and branchedchain alkene radicals. Alkenyl groups are essentially alkyl groups thatinclude at least one carbon-carbon double bond in the alkyl chain.Cycloalkenyl groups are essentially cycloalkyl groups that include atleast one carbon-carbon double bond in the cycloalkyl ring. The term“heteroalkenyl” as used herein refers to an alkenyl radical having atleast one carbon atom replaced by a heteroatom. Optionally the at leastone heteroatom is selected from O, S, N, P, B, Si, and Se, preferably,O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups arethose containing two to fifteen carbon atoms. Additionally, the alkenyl,cycloalkenyl, or heteroalkenyl group may be optionally substituted.

The term “alkynyl” refers to and includes both straight and branchedchain alkyne radicals. Alkynyl groups are essentially alkyl groups thatinclude at least one carbon-carbon triple bond in the alkyl chain.Preferred alkynyl groups are those containing two to fifteen carbonatoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” are used interchangeably and refer toan alkyl group that is substituted with an aryl group. Additionally, thearalkyl group may be optionally substituted.

The term “heterocyclic group” refers to and includes aromatic andnon-aromatic cyclic radicals containing at least one heteroatom.Optionally the at least one heteroatom is selected from O, S, N, P, B,Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals maybe used interchangeably with heteroaryl. Preferred hetero-non-aromaticcyclic groups are those containing 3 to 7 ring atoms which includes atleast one hetero atom, and includes cyclic amines such as morpholino,piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers,such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and thelike. Additionally, the heterocyclic group may be optionallysubstituted.

The term “aryl” refers to and includes both single-ring aromatichydrocarbyl groups and polycyclic aromatic ring systems. The polycyclicrings may have two or more rings in which two carbons are common to twoadjoining rings (the rings are “fused”) wherein at least one of therings is an aromatic hydrocarbyl group, e.g., the other rings can becycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.Preferred aryl groups are those containing six to thirty carbon atoms,preferably six to twenty carbon atoms, more preferably six to twelvecarbon atoms. Especially preferred is an aryl group having six carbons,ten carbons or twelve carbons. Suitable aryl groups include phenyl,biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene,anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene,perylene, and azulene, preferably phenyl, biphenyl, triphenyl,triphenylene, fluorene, and naphthalene. Additionally, the aryl groupmay be optionally substituted.

The term “heteroaryl” refers to and includes both single-ring aromaticgroups and polycyclic aromatic ring systems that include at least oneheteroatom. The heteroatoms include, but are not limited to O, S, N, P,B, Si, and Se. In many instances, O, S, or N are the preferredheteroatoms. Hetero-single ring aromatic systems are preferably singlerings with 5 or 6 ring atoms, and the ring can have from one to sixheteroatoms. The hetero-polycyclic ring systems can have two or morerings in which two atoms are common to two adjoining rings (the ringsare “fused”) wherein at least one of the rings is a heteroaryl, e.g.,the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles,and/or heteroaryls. The hetero-polycyclic aromatic ring systems can havefrom one to six heteroatoms per ring of the polycyclic aromatic ringsystem. Preferred heteroaryl groups are those containing three to thirtycarbon atoms, preferably three to twenty carbon atoms, more preferablythree to twelve carbon atoms. Suitable heteroaryl groups includedibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene,benzofuran, benzothiophene, benzoselenophene, carbazole,indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole,triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole,thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine,oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole,indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline,isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine,phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine,phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine,preferably dibenzothiophene, dibenzofuran, dibenzoselenophene,carbazole, indolocarbazole, imidazole, pyridine, triazine,benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine,and aza-analogs thereof. Additionally, the heteroaryl group may beoptionally substituted.

Of the aryl and heteroaryl groups listed above, the groups oftriphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran,dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine,pyrazine, pyrimidine, triazine, and benzimidazole, and the respectiveaza-analogs of each thereof are of particular interest.

The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl,and heteroaryl, as used herein, are independently unsubstituted, orindependently substituted, with one or more general substituents.

In many instances, the general substituents are selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl,carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, boryl, and combinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl,and combinations thereof.

In some instances, the more preferred general substituents are selectedfrom the group consisting of deuterium, fluorine, alkyl, cycloalkyl,alkoxy, aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, andcombinations thereof.

In yet other instances, the most preferred general substituents areselected from the group consisting of deuterium, fluorine, alkyl,cycloalkyl, aryl, heteroaryl, and combinations thereof.

The terms “substituted” and “substitution” refer to a substituent otherthan H that is bonded to the relevant position, e.g., a carbon ornitrogen. For example, when R¹ represents mono-substitution, then one R¹must be other than H (i.e., a substitution). Similarly, when R¹represents di-substitution, then two of R¹ must be other than H.Similarly, when R¹ represents zero or no substitution, R′, for example,can be a hydrogen for available valencies of ring atoms, as in carbonatoms for benzene and the nitrogen atom in pyrrole, or simply representsnothing for ring atoms with fully filled valencies, e.g., the nitrogenatom in pyridine. The maximum number of substitutions possible in a ringstructure will depend on the total number of available valencies in thering atoms.

As used herein, “combinations thereof” indicates that one or moremembers of the applicable list are combined to form a known orchemically stable arrangement that one of ordinary skill in the art canenvision from the applicable list. For example, an alkyl and deuteriumcan be combined to form a partial or fully deuterated alkyl group; ahalogen and alkyl can be combined to form a halogenated alkylsubstituent; and a halogen, alkyl, and aryl can be combined to form ahalogenated arylalkyl. In one instance, the term substitution includes acombination of two to four of the listed groups. In another instance,the term substitution includes a combination of two to three groups. Inyet another instance, the term substitution includes a combination oftwo groups. Preferred combinations of substituent groups are those thatcontain up to fifty atoms that are not hydrogen or deuterium, or thosewhich include up to forty atoms that are not hydrogen or deuterium, orthose that include up to thirty atoms that are not hydrogen ordeuterium. In many instances, a preferred combination of substituentgroups will include up to twenty atoms that are not hydrogen ordeuterium.

The “aza” designation in the fragments described herein, i.e.aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more ofthe C—H groups in the respective aromatic ring can be replaced by anitrogen atom, for example, and without any limitation, azatriphenyleneencompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. Oneof ordinary skill in the art can readily envision other nitrogen analogsof the aza-derivatives described above, and all such analogs areintended to be encompassed by the terms as set forth herein.

As used herein, “deuterium” refers to an isotope of hydrogen. Deuteratedcompounds can be readily prepared using methods known in the art. Forexample, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, andU.S. Pat. Application Pub. No. US 2011/0037057, which are herebyincorporated by reference in their entireties, describe the making ofdeuterium-substituted organometallic complexes. Further reference ismade to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt etal., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which areincorporated by reference in their entireties, describe the deuterationof the methylene hydrogens in benzyl amines and efficient pathways toreplace aromatic ring hydrogens with deuterium, respectively.

It is to be understood that when a molecular fragment is described asbeing a substituent or otherwise attached to another moiety, its namemay be written as if it were a fragment (e.g. phenyl, phenylene,naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g.benzene, naphthalene, dibenzofuran). As used herein, these differentways of designating a substituent or attached fragment are considered tobe equivalent.

In some instance, a pair of adjacent substituents can be optionallyjoined or fused into a ring. The preferred ring is a five, six, orseven-membered carbocyclic or heterocyclic ring, includes both instanceswhere the portion of the ring formed by the pair of substituents issaturated and where the portion of the ring formed by the pair ofsubstituents is unsaturated. As used herein, “adjacent” means that thetwo substituents involved can be on the same ring next to each other, oron two neighboring rings having the two closest available substitutablepositions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in anaphthalene, as long as they can form a stable fused ring system.

B. The Compounds of the Present Disclosure

In one aspect, the present disclosure provides a compound comprising afirst ligand L_(A) of Formula I

In Formula I: ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; where the first group is selectedfrom the group consisting of:

where the asterisks in each structure indicate adjacent C atoms that areon ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; the ligand L_(A)is complexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.

In some embodiments of the compound, each R, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the preferred general substituents defined herein.

In some embodiments, Z¹ and Z⁴ are N, and Z² and Z³ are C. In someembodiments, R^(C) is a hydrogen or a substituent selected from thegroup consisting of deuterium, alkyl, heteroalkyl, cycloalkyl,heterocycloalkyl, aryl, heteroaryl, and combinations thereof. In someembodiments, ring A is selected from the group consisting of benzene,pyridine, pyrazine, pyridazine, triazole, pyrrole, pyrroledione,oxadiazole, thiadiazole, and selenadiazole. In some embodiments, ring Bis a 6-membered aromatic ring.

In some embodiments, two adjacent R^(B) substituents can join togetherto form a 6-membered aromatic ring fused to ring B. In some embodiments,Z⁵ is C.

In some embodiments, ring A is a benzene ring, and two adjacent R^(A)substituents can join together to form a ring fused to ring A, whereinthe two adjacent R^(A) substituents are independently selected from thegroup consisting of:

In some embodiments, M is selected from the group consisting of Os, Ir,Pd, Pt, Cu, Ag, and Au. In some embodiments, M is Ir or Pt. In someembodiments, M is coordinated to a substituted or unsubstitutedacetylacetonate ligand.

In some embodiments, the first ligand L_(A) is selected from the groupconsisting of:

and Z⁶ and Z⁷ are each independently C or N.

In some embodiments, the first ligand L_(A) is selected from the groupconsisting of:

L_(Ai-1), where i=1 to 200, that are based on Formula 1

L_(Ai-2), where i=1 to 200, that are based on Formula 2

L_(Ai-3), where i=1 to 200, that are based on Formula 3

L_(Ai-4), where i=1 to 200, that are based on Formula 4

L_(Ai-5), where i=1 to 200, that are based on Formula 5

L_(Ai-6), where i=1 to 200, that are based on Formula 6

L_(Ai-7), where i=1 to 200, that are based on Formula 7

L_(Ai-8), where i=1 to 200, that are based on Formula 8

L_(Ai-9), where i=1 to 200, that are based on Formula 9

L_(Ai-10), where i=1 to 200, that are based on Formula 10

L_(Ai-11), where i=1 to 200, that are based on Formula 11

L_(Ai-12), where i=1 to 200, that are based on Formula 12

L_(Ai-13), where i=1 to 200, that are based on Formula 13

L_(Ai-14), where i=1 to 200, that are based on Formula 14

L_(Ai-15), where i=1 to 200, that are based on Formula 15

L_(Ai-16), where i=1 to 200, that are based on Formula 16

L_(Ai-17), where i=1 to 200, that are based on Formula 17

L_(Ai-18), where i=1 to 200, that are based on Formula 18

L_(Ai-19), where i=1 to 200, that are based on Formula 19

where R^(D) and G are defined as follows:

L_(Ai) R^(D) G L_(A1) R¹ G¹ L_(A2) R¹ G² L_(A3) R¹ G³ L_(A4) R¹ G⁴L_(A5) R¹ G⁵ L_(A6) R¹ G⁶ L_(A7) R¹ G⁷ L_(A8) R¹ G⁸ L_(A9) R¹ G⁹ L_(A10)R¹ G¹⁰ L_(A11) R² G¹ L_(A12) R² G² L_(A13) R² G³ L_(A14) R² G⁴ L_(A15)R² G⁵ L_(A16) R² G⁶ L_(A17) R² G⁷ L_(A18) R² G⁸ L_(A19) R² G⁹ L_(A20) R²G¹⁰ L_(A21) R³ G¹ L_(A22) R³ G² L_(A23) R³ G³ L_(A24) R³ G⁴ L_(A25) R³G⁵ L_(A26) R³ G⁶ L_(A27) R³ G⁷ L_(A28) R³ G⁸ L_(A29) R³ G⁹ L_(A30) R³G¹⁰ L_(A31) R⁴ G¹ L_(A32) R⁴ G² L_(A33) R⁴ G³ L_(A34) R⁴ G⁴ L_(A35) R⁴G⁵ L_(A36) R⁴ G⁶ L_(A37) R⁴ G⁷ L_(A38) R⁴ G⁸ L_(A39) R⁴ G⁹ L_(A40) R⁴G¹⁰ L_(A41) R⁵ G¹ L_(A42) R⁵ G² L_(A43) R⁵ G³ L_(A44) R⁵ G⁴ L_(A45) R⁵G⁵ L_(A46) R⁵ G⁶ L_(A47) R⁵ G⁷ L_(A48) R⁵ G⁸ L_(A49) R⁵ G⁹ L_(A50) R⁵G¹⁰ L_(A51) R⁶ G¹ L_(A52) R⁶ G² L_(A53) R⁶ G³ L_(A54) R⁶ G⁴ L_(A55) R⁶G⁵ L_(A56) R⁶ G⁶ L_(A57) R⁶ G⁷ L_(A58) R⁶ G⁸ L_(A59) R⁶ G⁹ L_(A60) R⁶G¹⁰ L_(A61) R⁷ G¹ L_(A62) R⁷ G² L_(A63) R⁷ G³ L_(A64) R⁷ G⁴ L_(A65) R⁷G⁵ L_(A66) R⁷ G⁶ L_(A67) R⁷ G⁷ L_(A68) R⁷ G⁸ L_(A69) R⁷ G⁹ L_(A70) R⁷G¹⁰ L_(A71) R⁸ G¹ L_(A72) R⁸ G² L_(A73) R⁸ G³ L_(A74) R⁸ G⁴ L_(A75) R⁸G⁵ L_(A76) R⁸ G⁶ L_(A77) R⁸ G⁷ L_(A78) R⁸ G⁸ L_(A79) R⁸ G⁹ L_(A80) R⁸G¹⁰ L_(A81) R⁹ G¹ L_(A82) R⁹ G² L_(A83) R⁹ G³ L_(A84) R⁹ G⁴ L_(A85) R⁹G⁵ L_(A86) R⁹ G⁶ L_(A87) R⁹ G⁷ L_(A88) R⁹ G⁸ L_(A89) R⁹ G⁹ L_(A90) R⁹G¹⁰ L_(A91) R¹⁰ G¹ L_(A92) R¹⁰ G² L_(A93) R¹⁰ G³ L_(A94) R¹⁰ G⁴ L_(A95)R¹⁰ G⁵ L_(A96) R¹⁰ G⁶ L_(A97) R¹⁰ G⁷ L_(A98) R¹⁰ G⁸ L_(A99) R¹⁰ G⁹L_(A100) R¹⁰ G¹⁰ L_(A101) R¹¹ G² L_(A102) R¹¹ G² L_(A103) R¹¹ G³L_(A104) R¹¹ G⁴ L_(A105) R¹¹ G⁵ L_(A106) R¹¹ G⁶ L_(A107) R¹¹ G⁷ L_(A108)R¹¹ G⁸ L_(A109) R¹¹ G⁹ L_(A110) R¹¹ G¹⁰ L_(A111) R¹² G¹ L_(A112) R¹² G²L_(A113) R¹² G³ L_(A114) R¹² G⁴ L_(A115) R¹² G⁵ L_(A116) R¹² G⁶ L_(A117)R¹² G⁷ L_(A118) R¹² G⁸ L_(A119) R¹² G⁹ L_(A120) R¹² G¹⁰ L_(A121) R¹³ G¹L_(A122) R¹³ G² L_(A123) R¹³ G³ L_(A124) R¹³ G⁴ L_(A125) R¹³ G⁵ L_(A126)R¹³ G⁶ L_(A127) R¹³ G⁷ L_(A128) R¹³ G⁸ L_(A129) R¹³ G⁹ L_(A130) R¹³ G¹⁰L_(A131) R¹⁴ G¹ L_(A132) R¹⁴ G² L_(A133) R¹⁴ G³ L_(A134) R¹⁴ G⁴ L_(A135)R¹⁴ G⁵ L_(A136) R¹⁴ G⁶ L_(A137) R¹⁴ G⁷ L_(A138) R¹⁴ G⁸ L_(A139) R¹⁴ G⁹L_(A140) R¹⁴ G¹⁰ L_(A141) R¹⁵ G¹ L_(A142) R¹⁵ G² L_(A143) R¹⁵ G³L_(A144) R¹⁵ G⁴ L_(A145) R¹⁵ G⁵ L_(A146) R¹⁵ G⁶ L_(A147) R¹⁵ G⁷ L_(A148)R¹⁵ G⁸ L_(A149) R¹⁵ G⁹ L_(A150) R¹⁵ G¹⁰ L_(A151) R¹⁶ G² L_(A152) R¹⁶ G²L_(A153) R¹⁶ G³ L_(A154) R¹⁶ G⁴ L_(A155) R¹⁶ G⁵ L_(A156) R¹⁶ G⁶ L_(A157)R¹⁶ G⁷ L_(A158) R¹⁶ G⁸ L_(A159) R¹⁶ G⁹ L_(A160) R¹⁶ G¹⁰ L_(A161) R¹⁷ G¹L_(A162) R¹⁷ G² L_(A163) R¹⁷ G³ L_(A164) R¹⁷ G⁴ L_(A165) R¹⁷ G⁵ L_(A166)R¹⁷ G⁶ L_(A167) R¹⁷ G⁷ L_(A168) R¹⁷ G⁸ L_(A169) R¹⁷ G⁹ L_(A170) R¹⁷ G¹⁰L_(A171) R¹⁸ G¹ L_(A172) R¹⁸ G² L_(A173) R¹⁸ G³ L_(A174) R¹⁸ G⁴ L_(A175)R¹⁸ G⁵ L_(A176) R¹⁸ G⁶ L_(A177) R¹⁸ G⁷ L_(A178) R¹⁸ G⁸ L_(A179) R¹⁸ G⁹L_(A180) R¹⁸ G¹⁰ L_(A181) R¹⁹ G¹ L_(A182) R¹⁹ G² L_(A183) R¹⁹ G³L_(A184) R¹⁹ G⁴ L_(A185) R¹⁹ G⁵ L_(A186) R¹⁹ G⁶ L_(A187) R¹⁹ G⁷ L_(A188)R¹⁹ G⁸ L_(A189) R¹⁹ G⁹ L_(A190) R¹⁹ G¹⁰ L_(A191) R²⁰ G¹ L_(A192) R²⁰ G²L_(A193) R²⁰ G³ L_(A194) R²⁰ G⁴ L_(A195) R²⁰ G⁵ L_(A196) R²⁰ G⁶ L_(A197)R²⁰ G⁷ L_(A198) R²⁰ G⁸ L_(A199) R²⁰ G⁹ L_(A200) R²⁰ G¹⁰L_(Ai-20), where i=201 to 600, that are based on Formula 20

L_(Ai-21), where i=201 to 600, that are based on Formula 21

L_(Ai-22), where i=201 to 600, that are based on Formula 22

L_(Ai-23), where i=201 to 600, that are based on Formula 23

L_(Ai-24), where i=201 to 600, that are based on Formula 24

L_(Ai-25), where i=201 to 600, that are based on Formula 25

L_(Ai-26), where i=201 to 600, that are based on Formula 26

L_(Ai-27), where i=201 to 600, that are based on Formula 27

L_(Ai-28), where i=201 to 600, that are based on Formula 28

L_(Ai-29), where i=201 to 600, that are based on Formula 29

where R, R^(D) and G are defined as follows:

L_(Ai) R R^(D) G L_(A201) R¹ R¹ G¹ L_(A202) R¹ R¹ G² L_(A203) R¹ R¹ G³L_(A204) R¹ R¹ G⁴ L_(A205) R¹ R¹ G⁵ L_(A206) R¹ R¹ G⁶ L_(A207) R¹ R¹ G⁷L_(A208) R¹ R¹ G⁸ L_(A209) R¹ R¹ G⁹ L_(A210) R¹ R¹ G¹⁰ L_(A211) R² R¹ G¹L_(A212) R² R¹ G² L_(A213) R² R¹ G³ L_(A214) R² R¹ G⁴ L_(A215) R² R¹ G⁵L_(A216) R² R¹ G⁶ L_(A217) R² R¹ G⁷ L_(A218) R² R¹ G⁸ L_(A219) R² R¹ G⁹L_(A220) R² R¹ G¹⁰ L_(A221) R³ R¹ G¹ L_(A222) R³ R¹ G² L_(A223) R³ R¹ G³L_(A224) R³ R¹ G⁴ L_(A225) R³ R¹ G⁵ L_(A226) R³ R¹ G⁶ L_(A227) R³ R¹ G⁷L_(A228) R³ R¹ G⁸ L_(A229) R³ R¹ G⁹ L_(A230) R³ R¹ G¹⁰ L_(A231) R⁴ R¹ G¹L_(A232) R⁴ R¹ G² L_(A233) R⁴ R¹ G³ L_(A234) R⁴ R¹ G⁴ L_(A235) R⁴ R¹ G⁵L_(A236) R⁴ R¹ G⁶ L_(A237) R⁴ R¹ G⁷ L_(A238) R⁴ R¹ G⁸ L_(A239) R⁴ R¹ G⁹L_(A240) R⁴ R¹ G¹⁰ L_(A241) R⁵ R¹ G¹ L_(A242) R⁵ R¹ G² L_(A243) R⁵ R¹ G³L_(A244) R⁵ R¹ G⁴ L_(A245) R⁵ R¹ G⁵ L_(A246) R⁵ R¹ G⁶ L_(A247) R⁵ R¹ G⁷L_(A248) R⁵ R¹ G⁸ L_(A249) R⁵ R¹ G⁹ L_(A250) R⁵ R¹ G¹⁰ L_(A251) R⁶ R¹ G¹L_(A252) R⁶ R¹ G² L_(A253) R⁶ R¹ G³ L_(A254) R⁶ R¹ G⁴ L_(A255) R⁶ R¹ G⁵L_(A256) R⁶ R¹ G⁶ L_(A257) R⁶ R¹ G⁷ L_(A258) R⁶ R¹ G⁸ L_(A259) R⁶ R¹ G⁹L_(A260) R⁶ R¹ G¹⁰ L_(A261) R⁷ R¹ G¹ L_(A262) R⁷ R¹ G² L_(A263) R⁷ R¹ G³L_(A264) R⁷ R¹ G⁴ L_(A265) R⁷ R¹ G⁵ L_(A266) R⁷ R¹ G⁶ L_(A267) R⁷ R¹ G⁷L_(A268) R⁷ R¹ G⁸ L_(A269) R⁷ R¹ G⁹ L_(A270) R⁷ R¹ G¹⁰ L_(A271) R⁸ R¹ G¹L_(A272) R⁸ R¹ G² L_(A273) R⁸ R¹ G³ L_(A274) R⁸ R¹ G⁴ L_(A275) R⁸ R¹ G⁵L_(A276) R⁸ R¹ G⁶ L_(A277) R⁸ R¹ G⁷ L_(A278) R⁸ R¹ G⁸ L_(A279) R⁸ R¹ G⁹L_(A280) R⁸ R¹ G¹⁰ L_(A281) R⁹ R¹ G¹ L_(A282) R⁹ R¹ G² L_(A283) R⁹ R¹ G³L_(A283) R⁹ R¹ G⁴ L_(A283) R⁹ R¹ G⁵ L_(A283) R⁹ R¹ G⁶ L_(A283) R⁹ R¹ G⁷L_(A288) R⁹ R¹ G⁸ L_(A289) R⁹ R¹ G⁹ L_(A290) R⁹ R¹ G¹⁰ L_(A291) R¹⁰ R¹G¹ L_(A292) R¹⁰ R¹ G² L_(A293) R¹⁰ R¹ G³ L_(A294) R¹⁰ R¹ G⁴ L_(A295) R¹⁰R¹ G⁵ L_(A296) R¹⁰ R¹ G⁶ L_(A297) R¹⁰ R¹ G⁷ L_(A298) R¹⁰ R¹ G⁸ L_(A299)R¹⁰ R¹ G⁹ L_(A300) R¹⁰ R¹ G¹⁰ L_(A301) R¹¹ R¹ G¹ L_(A302) R¹¹ R¹ G²L_(A303) R¹¹ R¹ G³ L_(A304) R¹¹ R¹ G⁴ L_(A305) R¹¹ R¹ G⁵ L_(A306) R¹¹ R¹G⁶ L_(A307) R¹¹ R¹ G⁷ L_(A308) R¹¹ R¹ G⁸ L_(A309) R¹¹ R¹ G⁹ L_(A310) R¹¹R¹ G¹⁰ L_(A311) R¹² R¹ G¹ L_(A312) R¹² R¹ G² L_(A313) R¹² R¹ G³ L_(A314)R¹² R¹ G⁴ L_(A315) R¹² R¹ G⁵ L_(A316) R¹² R¹ G⁶ L_(A317) R¹² R¹ G⁷L_(A318) R¹² R¹ G⁸ L_(A319) R¹² R¹ G⁹ L_(A320) R¹² R¹ G¹⁰ L_(A321) R¹³R¹ G¹ L_(A322) R¹³ R¹ G² L_(A323) R¹³ R¹ G³ L_(A324) R¹³ R¹ G⁴ L_(A325)R¹³ R¹ G⁵ L_(A326) R¹³ R¹ G⁶ L_(A327) R¹³ R¹ G⁷ L_(A328) R¹³ R¹ G⁸L_(A329) R¹³ R¹ G⁹ L_(A330) R¹³ R¹ G¹⁰ L_(A331) R¹⁴ R¹ G¹ L_(A332) R¹⁴R¹ G² L_(A333) R¹⁴ R¹ G³ L_(A334) R¹⁴ R¹ G⁴ L_(A335) R¹⁴ R¹ G⁵ L_(A336)R¹⁴ R¹ G⁶ L_(A337) R¹⁴ R¹ G⁷ L_(A338) R¹⁴ R¹ G⁸ L_(A339) R¹⁴ R¹ G⁹L_(A340) R¹⁴ R¹ G¹⁰ L_(A341) R¹⁵ R¹ G¹ L_(A342) R¹⁵ R¹ G² L_(A343) R¹⁵R¹ G³ L_(A344) R¹⁵ R¹ G⁴ L_(A345) R¹⁵ R¹ G⁵ L_(A346) R¹⁵ R¹ G⁶ L_(A347)R¹⁵ R¹ G⁷ L_(A348) R¹⁵ R¹ G⁸ L_(A349) R¹⁵ R¹ G⁹ L_(A350) R¹⁵ R¹ G¹⁰L_(A351) R¹⁶ R¹ G¹ L_(A352) R¹⁶ R¹ G² L_(A353) R¹⁶ R¹ G³ L_(A354) R¹⁶ R¹G⁴ L_(A355) R¹⁶ R¹ G⁵ L_(A356) R¹⁶ R¹ G⁶ L_(A357) R¹⁶ R¹ G⁷ L_(A358) R¹⁶R¹ G⁸ L_(A359) R¹⁶ R¹ G⁹ L_(A360) R¹⁶ R¹ G¹⁰ L_(A361) R¹⁷ R¹ G¹ L_(A362)R¹⁷ R¹ G² L_(A363) R¹⁷ R¹ G³ L_(A364) R¹⁷ R¹ G⁴ L_(A365) R¹⁷ R¹ G⁵L_(A366) R¹⁷ R¹ G⁶ L_(A367) R¹⁷ R¹ G⁷ L_(A368) R¹⁷ R¹ G⁸ L_(A369) R¹⁷ R¹G⁹ L_(A370) R¹⁷ R¹ G¹⁰ L_(A371) R¹⁸ R¹ G¹ L_(A372) R¹⁸ R¹ G² L_(A373)R¹⁸ R¹ G³ L_(A374) R¹⁸ R¹ G⁴ L_(A375) R¹⁸ R¹ G⁵ L_(A376) R¹⁸ R¹ G⁶L_(A377) R¹⁸ R¹ G⁷ L_(A378) R¹⁸ R¹ G⁸ L_(A379) R¹⁸ R¹ G⁹ L_(A380) R¹⁸ R¹G¹⁰ L_(A381) R¹⁹ R¹ G¹ L_(A382) R¹⁹ R¹ G² L_(A383) R¹⁹ R¹ G³ L_(A384)R¹⁹ R¹ G⁴ L_(A385) R¹⁹ R¹ G⁵ L_(A386) R¹⁹ R¹ G⁶ L_(A387) R¹⁹ R¹ G⁷L_(A388) R¹⁹ R¹ G⁸ L_(A389) R¹⁹ R¹ G⁹ L_(A390) R¹⁹ R¹ G¹⁰ L_(A391) R²⁰R¹ G¹ L_(A392) R²⁰ R¹ G² L_(A393) R²⁰ R¹ G³ L_(A394) R²⁰ R¹ G⁴ L_(A395)R²⁰ R¹ G⁵ L_(A396) R²⁰ R¹ G⁶ L_(A397) R²⁰ R¹ G⁷ L_(A398) R²⁰ R¹ G⁸L_(A399) R²⁰ R¹ G⁹ L_(A400) R²⁰ R¹ G¹⁰ L_(A401) R¹ R⁴ G¹ L_(A402) R¹ R⁴G² L_(A403) R¹ R⁴ G³ L_(A404) R¹ R⁴ G⁴ L_(A405) R¹ R⁴ G⁵ L_(A406) R¹ R⁴G⁶ L_(A407) R¹ R⁴ G⁷ L_(A408) R¹ R⁴ G⁸ L_(A409) R¹ R⁴ G⁹ L_(A410) R¹ R⁴G¹⁰ L_(A411) R² R⁴ G¹ L_(A412) R² R⁴ G² L_(A413) R² R⁴ G³ L_(A414) R² R⁴G⁴ L_(A415) R² R⁴ G⁵ L_(A416) R² R⁴ G⁶ L_(A417) R² R⁴ G⁷ L_(A418) R² R⁴G⁸ L_(A419) R² R⁴ G⁹ L_(A420) R² R⁴ G¹⁰ L_(A421) R³ R⁴ G¹ L_(A422) R³ R⁴G² L_(A423) R³ R⁴ G³ L_(A424) R³ R⁴ G⁴ L_(A425) R³ R⁴ G⁵ L_(A426) R³ R⁴G⁶ L_(A427) R³ R⁴ G⁷ L_(A428) R³ R⁴ G⁸ L_(A429) R³ R⁴ G⁹ L_(A430) R³ R⁴G¹⁰ L_(A431) R⁴ R⁴ G¹ L_(A432) R⁴ R⁴ G² L_(A433) R⁴ R⁴ G³ L_(A434) R⁴ R⁴G⁴ L_(A435) R⁴ R⁴ G⁵ L_(A436) R⁴ R⁴ G⁶ L_(A437) R⁴ R⁴ G⁷ L_(A438) R⁴ R⁴G⁸ L_(A439) R⁴ R⁴ G⁹ L_(A440) R⁴ R⁴ G¹⁰ L_(A441) R⁵ R⁴ G¹ L_(A442) R⁵ R⁴G² L_(A443) R⁵ R⁴ G³ L_(A444) R⁵ R⁴ G⁴ L_(A445) R⁵ R⁴ G⁵ L_(A446) R⁵ R⁴G⁶ L_(A447) R⁵ R⁴ G⁷ L_(A448) R⁵ R⁴ G⁸ L_(A449) R⁵ R⁴ G⁹ L_(A450) R⁵ R⁴G¹⁰ L_(A451) R⁶ R⁴ G¹ L_(A452) R⁶ R⁴ G² L_(A453) R⁶ R⁴ G³ L_(A454) R⁶ R⁴G⁴ L_(A455) R⁶ R⁴ G⁵ L_(A456) R⁶ R⁴ G⁶ L_(A457) R⁶ R⁴ G⁷ L_(A458) R⁶ R⁴G⁸ L_(A459) R⁶ R⁴ G⁹ L_(A460) R⁶ R⁴ G¹⁰ L_(A461) R⁷ R⁴ G¹ L_(A462) R⁷ R⁴G² L_(A463) R⁷ R⁴ G³ L_(A464) R⁷ R⁴ G⁴ L_(A465) R⁷ R⁴ G⁵ L_(A466) R⁷ R⁴G⁶ L_(A467) R⁷ R⁴ G⁸ L_(A468) R⁷ R⁴ G⁹ L_(A469) R⁷ R⁴ G¹⁰ L_(A470) R⁸ R⁴G¹ L_(A471) R⁸ R⁴ G² L_(A472) R⁸ R⁴ G³ L_(A473) R⁸ R⁴ G⁴ L_(A474) R⁸ R⁴G⁵ L_(A475) R⁸ R⁴ G⁶ L_(A476) R⁸ R⁴ G⁷ L_(A477) R⁸ R⁴ G⁸ L_(A478) R⁸ R⁴G⁹ L_(A479) R⁸ R⁴ G¹⁰ L_(A480) R⁹ R⁴ G¹ L_(A481) R⁹ R⁴ G² L_(A482) R⁹ R⁴G³ L_(A483) R⁹ R⁴ G⁴ L_(A484) R⁹ R⁴ G⁵ L_(A485) R⁹ R⁴ G⁶ L_(A486) R⁹ R⁴G⁷ L_(A487) R⁹ R⁴ G⁸ L_(A488) R⁹ R⁴ G⁹ L_(A489) R⁹ R⁴ G¹⁰ L_(A490) R¹⁰R⁴ G¹ L_(A491) R¹⁰ R⁴ G² L_(A492) R¹⁰ R⁴ G³ L_(A493) R¹⁰ R⁴ G⁴ L_(A494)R¹⁰ R⁴ G⁵ L_(A495) R¹⁰ R⁴ G⁶ L_(A496) R¹⁰ R⁴ G⁷ L_(A497) R¹⁰ R⁴ G⁸L_(A498) R¹⁰ R⁴ G⁹ L_(A499) R¹⁰ R⁴ G¹⁰ L_(A500) R¹¹ R⁴ G¹ L_(A501) R¹¹R⁴ G² L_(A502) R¹¹ R⁴ G³ L_(A503) R¹¹ R⁴ G⁴ L_(A504) R¹¹ R⁴ G⁵ L_(A505)R¹¹ R⁴ G⁶ L_(A506) R¹¹ R⁴ G⁷ L_(A507) R¹¹ R⁴ G⁸ L_(A508) R¹¹ R⁴ G⁹L_(A509) R¹¹ R⁴ G¹⁰ L_(A510) R¹² R⁴ G¹ L_(A511) R¹² R⁴ G² L_(A512) R¹²R⁴ G³ L_(A513) R¹² R⁴ G⁴ L_(A514) R¹² R⁴ G⁵ L_(A515) R¹² R⁴ G⁶ L_(A516)R¹² R⁴ G⁷ L_(A517) R¹² R⁴ G⁸ L_(A518) R¹² R⁴ G⁹ L_(A519) R¹² R⁴ G¹⁰L_(A520) R¹³ R⁴ G¹ L_(A521) R¹³ R⁴ G² L_(A522) R¹³ R⁴ G³ L_(A523) R¹³ R⁴G⁴ L_(A524) R¹³ R⁴ G⁵ L_(A525) R¹³ R⁴ G⁶ L_(A526) R¹³ R⁴ G⁷ L_(A527) R¹³R⁴ G⁸ L_(A528) R¹³ R⁴ G⁹ L_(A529) R¹³ R⁴ G¹⁰ L_(A530) R¹⁴ R⁴ G¹ L_(A531)R¹⁴ R⁴ G² L_(A532) R¹⁴ R⁴ G³ L_(A533) R¹⁴ R⁴ G⁴ L_(A534) R¹⁴ R⁴ G⁵L_(A535) R¹⁴ R⁴ G⁶ L_(A536) R¹⁴ R⁴ G⁷ L_(A537) R¹⁴ R⁴ G⁸ L_(A538) R¹⁴ R⁴G⁹ L_(A539) R¹⁴ R⁴ G¹⁰ L_(A540) R¹⁵ R⁴ G¹ L_(A541) R¹⁵ R⁴ G² L_(A542)R¹⁵ R⁴ G³ L_(A543) R¹⁵ R⁴ G⁴ L_(A544) R¹⁵ R⁴ G⁵ L_(A545) R¹⁵ R⁴ G⁶L_(A546) R¹⁵ R⁴ G⁷ L_(A547) R¹⁵ R⁴ G⁸ L_(A548) R¹⁵ R⁴ G⁹ L_(A549) R¹⁵ R⁴G¹⁰ L_(A550) R¹⁶ R⁴ G¹ L_(A551) R¹⁶ R⁴ G² L_(A552) R¹⁶ R⁴ G³ L_(A553)R¹⁶ R⁴ G⁴ L_(A554) R¹⁶ R⁴ G⁵ L_(A555) R¹⁶ R⁴ G⁶ L_(A556) R¹⁶ R⁴ G⁷L_(A557) R¹⁶ R⁴ G⁸ L_(A558) R¹⁶ R⁴ G⁹ L_(A559) R¹⁶ R⁴ G¹⁰ L_(A560) R¹⁷R⁴ G¹ L_(A561) R¹⁷ R⁴ G² L_(A562) R¹⁷ R⁴ G³ L_(A563) R¹⁷ R⁴ G⁴ L_(A564)R¹⁷ R⁴ G⁵ L_(A565) R¹⁷ R⁴ G⁶ L_(A566) R¹⁷ R⁴ G⁷ L_(A567) R¹⁷ R⁴ G⁸L_(A568) R¹⁷ R⁴ G⁹ L_(A569) R¹⁷ R⁴ G¹⁰ L_(A570) R¹⁸ R⁴ G¹ L_(A571) R¹⁸R⁴ G² L_(A572) R¹⁸ R⁴ G³ L_(A573) R¹⁸ R⁴ G⁴ L_(A574) R¹⁸ R⁴ G⁵ L_(A575)R¹⁸ R⁴ G⁶ L_(A576) R¹⁸ R⁴ G⁷ L_(A577) R¹⁸ R⁴ G⁸ L_(A578) R¹⁸ R⁴ G⁹L_(A579) R¹⁸ R⁴ G¹⁰ L_(A580) R¹⁹ R⁴ G¹ L_(A581) R¹⁹ R⁴ G² L_(A582) R¹⁹R⁴ G³ L_(A583) R¹⁹ R⁴ G⁴ L_(A584) R¹⁹ R⁴ G⁵ LA₅₈₅ R¹⁹ R⁴ G⁶ L_(A586) R¹⁹R⁴ G⁷ L_(A587) R¹⁹ R⁴ G⁸ L_(A588) R¹⁹ R⁴ G⁹ L_(A589) R¹⁹ R⁴ G¹⁰ L_(A590)R²⁰ R⁴ G¹ L_(A591) R²⁰ R⁴ G² L_(A592) R²⁰ R⁴ G³ L_(A593) R²⁰ R⁴ G⁴L_(A594) R²⁰ R⁴ G⁵ L_(A595) R²⁰ R⁴ G⁶ L_(A596) R²⁰ R⁴ G⁷ L_(A597) R²⁰ R⁴G⁸ L_(A598) R²⁰ R⁴ G⁹ L_(A599) R²⁰ R⁴ G¹⁰ L_(A600) R²⁰ R⁴ G¹⁰L_(Ai-30), where i=601 to 610, that are based on Formula 30

L_(Ai-31), where i=601 to 610, that are based on Formula 31

L_(Ai-32), where i=601 to 610, that are based on Formula 32

L_(Ai-33), where i=601 to 610, that are based on Formula 33

L_(Ai-34), where i=601 to 610, that are based on Formula 34

L_(Ai-35), where i=601 to 610, that are based on Formula 35

L_(Ai-36), where i=601 to 610, that are based on Formula 36

L_(Ai-37), where i=601 to 610, that are based on Formula 37

L_(Ai-38), where i=601 to 610, that are based on Formula 38

where G is defined as follows:

L_(Ai) G Ligand G L_(Ai) G L_(Ai) G L_(Ai) G L_(Ai) G L_(A601) G¹L_(A602) G² L_(A603) G³ L_(A604) G⁴ L_(A605) G⁵ L_(A606) G⁶ L_(A607) G⁷L_(A608) G⁸ L_(A609) G⁹ L_(A610) G¹⁰where R¹ to R²⁰ have the following structures:

andwhere G¹ to G¹⁰ have the following structures:

In some embodiments of the compound, the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), where the ligand L_(A) is as definedabove and L_(B) and L_(C) are each a bidentate ligand; and wherein x is1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidationstate of the metal M. In some embodiments, L_(B) can be selected fromthe group consisting of L_(B1) to L_(B263) whose structures are definedas follows:

andL_(C) can be selected from the group consisting of ligands L_(Cj), wherej is an integer from 1 to 768, where each L_(Cj) can have the structureof L_(Cj-I), having the structures based on a structure of

orL_(Cj-II), having the structures based on a structure of

wherein for each L_(Cj) in L_(Cj-I) and L_(Cj-II), R¹ and R² are definedas provided below:

L_(Cj) R¹ R² L_(C1) R^(D1) R^(D1) L_(C2) R^(D2) R^(D2) L_(C3) R^(D3)R^(D3) L_(C4) R^(D4) R^(D4) L_(C5) R^(D5) R^(D5) L_(C6) R^(D6) R^(D6)L_(C7) R^(D7) R^(D7) L_(C8) R^(D8) R^(D8) L_(C9) R^(D9) R^(D9) L_(C10)R^(D10) R^(D10) L_(C11) R^(D11) R^(D11) L_(C12) R^(D12) R^(D12) L_(C13)R^(D13) R^(D13) L_(C14) R^(D14) R^(D14) L_(C15) R^(D15) R^(D15) L_(C16)R^(D16) R^(D16) L_(C17) R^(D17) R^(D17) L_(C18) R^(D18) R^(D18) L_(C19)R^(D19) R^(D19) L_(C20) R^(D20) R^(D20) L_(C21) R^(D21) R^(D21) L_(C22)R^(D22) R^(D22) L_(C23) R^(D23) R^(D23) L_(C24) R^(D24) R^(D24) L_(C25)R^(D25) R^(D25) L_(C26) R^(D26) R^(D26) L_(C27) R^(D27) R^(D27) L_(C28)R^(D28) R^(D28) L_(C29) R^(D29) R^(D29) L_(C30) R^(D30) R^(D30) L_(C31)R^(D31) R^(D31) L_(C32) R^(D32) R^(D32) L_(C33) R^(D33) R^(D33) L_(C34)R^(D34) R^(D34) L_(C35) R^(D35) R^(D35) L_(C36) R^(D36) R^(D36) L_(C37)R^(D37) R^(D37) L_(C38) R^(D38) R^(D38) L_(C39) R^(D39) R^(D39) L_(C40)R^(D40) R^(D40) L_(C41) R^(D41) R^(D41) L_(C42) R^(D42) R^(D42) L_(C43)R^(D43) R^(D43) L_(C44) R^(D44) R^(D44) L_(C45) R^(D45) R^(D45) L_(C46)R^(D46) R^(D46) L_(C47) R^(D47) R^(D47) L_(C48) R^(D48) R^(D48) L_(C49)R^(D49) R^(D49) L_(C50) R^(D50) R^(D50) L_(C51) R^(D51) R^(D51) L_(C52)R^(D52) R^(D52) L_(C53) R^(D53) R^(D53) L_(C54) R^(D54) R^(D54) L_(C55)R^(D55) R^(D55) L_(C56) R^(D56) R^(D56) L_(C57) R^(D57) R^(D57) L_(C58)R^(D58) R^(D58) L_(C59) R^(D59) R^(D59) L_(C60) R^(D60) R^(D60) L_(C61)R^(D61) R^(D61) L_(C62) R^(D62) R^(D62) L_(C63) R^(D63) R^(D63) L_(C64)R^(D64) R^(D64) L_(C65) R^(D65) R^(D65) L_(C66) R^(D66) R^(D66) L_(C67)R^(D67) R^(D67) L_(C68) R^(D68) R^(D68) L_(C69) R^(D69) R^(D69) L_(C70)R^(D70) R^(D70) L_(C71) R^(D71) R^(D71) L_(C72) R^(D72) R^(D72) L_(C73)R^(D73) R^(D73) L_(C74) R^(D74) R^(D74) L_(C75) R^(D75) R^(D75) L_(C76)R^(D76) R^(D76) L_(C77) R^(D77) R^(D77) L_(C78) R^(D78) R^(D78) L_(C79)R^(D79) R^(D79) L_(C80) R^(D80) R^(D80) L_(C81) R^(D81) R^(D81) L_(C82)R^(D82) R^(D82) L_(C83) R^(D83) R^(D83) L_(C84) R^(D84) R^(D84) L_(C85)R^(D85) R^(D85) L_(C86) R^(D86) R^(D86) L_(C87) R^(D87) R^(D87) L_(C88)R^(D88) R^(D88) L_(C89) R^(D89) R^(D89) L_(C90) R^(D90) R^(D90) L_(C91)R^(D91) R^(D91) L_(C92) R^(D92) R^(D92) L_(C93) R^(D93) R^(D93) L_(C94)R^(D94) R^(D94) L_(C95) R^(D95) R^(D95) L_(C96) R^(D96) R^(D96) L_(C97)R^(D97) R^(D97) L_(C98) R^(D98) R^(D98) L_(C99) R^(D99) R^(D99) L_(C100)R^(D100) R^(D100) L_(C101) R^(D101) R^(D101) L_(C102) R^(D102) R^(D102)L_(C103) R^(D103) R^(D103) L_(C104) R^(D104) R^(D104) L_(C105) R^(D105)R^(D105) L_(C106) R^(D106) R^(D106) L_(C107) R^(D107) R^(D107) L_(C108)R^(D108) R^(D108) L_(C109) R^(D109) R^(D109) L_(C110) R^(D110) R^(D110)L_(C111) R^(D111) R^(D111) L_(C112) R^(D112) R^(D112) L_(C113) R^(D113)R^(D113) L_(C114) R^(D114) R^(D114) L_(C115) R^(D115) R^(D115) L_(C116)R^(D116) R^(D116) L_(C117) R^(D117) R^(D117) L_(C118) R^(D118) R^(D118)L_(C119) R^(D119) R^(D119) L_(C120) R^(D120) R^(D120) L_(C121) R^(D121)R^(D121) L_(C122) R^(D122) R^(D122) L_(C123) R^(D123) R^(D123) L_(C124)R^(D124) R^(D124) L_(C125) R^(D125) R^(D125) L_(C126) R^(D126) R^(D126)L_(C127) R^(D127) R^(D127) L_(C128) R^(D128) R^(D128) L_(C129) R^(D129)R^(D129) L_(C130) R^(D130) R^(D130) L_(C131) R^(D131) R^(D131) L_(C132)R^(D132) R^(D132) L_(C133) R^(D133) R^(D133) L_(C134) R^(D134) R^(D134)L_(C135) R^(D135) R^(D135) L_(C136) R^(D136) R^(D136) L_(C137) R^(D137)R^(D137) L_(C138) R^(D138) R^(D138) L_(C139) R^(D139) R^(D139) L_(C140)R^(D140) R^(D140) L_(C141) R^(D141) R^(D141) L_(C142) R^(D142) R^(D142)L_(C143) R^(D143) R^(D143) L_(C144) R^(D144) R^(D144) L_(C145) R^(D145)R^(D145) L_(C146) R^(D146) R^(D146) L_(C147) R^(D147) R^(D147) L_(C148)R^(D148) R^(D148) L_(C149) R^(D149) R^(D149) L_(C150) R^(D150) R^(D150)L_(C151) R^(D151) R^(D151) L_(C152) R^(D152) R^(D152) L_(C153) R^(D153)R^(D153) L_(C154) R^(D154) R^(D154) L_(C155) R^(D155) R^(D155) L_(C156)R^(D156) R^(D156) L_(C157) R^(D157) R^(D157) L_(C158) R^(D158) R^(D158)L_(C159) R^(D159) R^(D159) L_(C160) R^(D160) R^(D160) L_(C161) R^(D161)R^(D161) L_(C162) R^(D162) R^(D162) L_(C163) R^(D163) R^(D163) L_(C164)R^(D164) R^(D164) L_(C165) R^(D165) R^(D165) L_(C166) R^(D166) R^(D166)L_(C167) R^(D167) R^(D167) L_(C168) R^(D168) R^(D168) L_(C169) R^(D169)R^(D169) L_(C170) R^(D170) R^(D170) L_(C171) R^(D171) R^(D171) L_(C172)R^(D172) R^(D172) L_(C173) R^(D173) R^(D173) L_(C174) R^(D174) R^(D174)L_(C175) R^(D175) R^(D175) L_(C176) R^(D176) R^(D176) L_(C177) R^(D177)R^(D177) L_(C178) R^(D178) R^(D178) L_(C179) R^(D179) R^(D179) L_(C180)R^(D180) R^(D180) L_(C181) R^(D181) R^(D181) L_(C182) R^(D182) R^(D182)L_(C183) R^(D183) R^(D183) L_(C184) R^(D184) R^(D184) L_(C185) R^(D185)R^(D185) L_(C186) R^(D186) R^(D186) L_(C187) R^(D187) R^(D187) L_(C188)R^(D188) R^(D188) L_(C189) R^(D189) R^(D189) L_(C190) R^(D190) R^(D190)L_(C191) R^(D191) R^(D191) L_(C192) R^(D192) R^(D192) L_(C193) R^(D1)R^(D3) L_(C194) R^(D1) R^(D4) L_(C195) R^(D1) R^(D5) L_(C196) R^(D1)R^(D9) L_(C197) R^(D1) R^(D10) L_(C198) R^(D1) R^(D17) L_(C199) R^(D1)R^(D18) L_(C200) R^(D1) R^(D20) L_(C201) R^(D1) R^(D22) L_(C202) R^(D1)R^(D37) L_(C203) R^(D1) R^(D40) L_(C204) R^(D1) R^(D41) L_(C205) R^(D1)R^(D42) L_(C206) R^(D1) R^(D43) L_(C207) R^(D1) R^(D48) L_(C208) R^(D1)R^(D49) L_(C209) R^(D1) R^(D50) L_(C210) R^(D1) R^(D54) L_(C211) R^(D1)R^(D55) L_(C212) R^(D1) R^(D58) L_(C213) R^(D1) R^(D59) L_(C214) R^(D1)R^(D78) L_(C215) R^(D1) R^(D79) L_(C216) R^(D1) R^(D81) L_(C217) R^(D1)R^(D87) L_(C218) R^(D1) R^(D88) L_(C219) R^(D1) R^(D89) L_(C220) R^(D1)R^(D93) L_(C221) R^(D1) R^(D116) L_(C222) R^(D1) R^(D117) L_(C223)R^(D1) R^(D118) L_(C224) R^(D1) R^(D119) L_(C225) R^(D1) R^(D120)L_(C226) R^(D1) R^(D133) L_(C227) R^(D1) R^(D134) L_(C228) R^(D1)R^(D135) L_(C229) R^(D1) R^(D136) L_(C230) R^(D1) R^(D143) L_(C231)R^(D1) R^(D144) L_(C232) R^(D1) R^(D145) L_(C233) R^(D1) R^(D146)L_(C234) R^(D1) R^(D147) L_(C235) R^(D1) R^(D149) L_(C236) R^(D1)R^(D151) L_(C237) R^(D1) R^(D154) L_(C238) R^(D1) R^(D155) L_(C239)R^(D1) R^(D161) L_(C240) R^(D1) R^(D175) L_(C241) R^(D4) R^(D3) L_(C242)R^(D4) R^(D5) L_(C243) R^(D4) R^(D9) L_(C244) R^(D4) R^(D10) L_(C245)R^(D4) R^(D17) L_(C246) R^(D4) R^(D18) L_(C247) R^(D4) R^(D20) L_(C248)R^(D4) R^(D22) L_(C249) R^(D4) R^(D37) L_(C250) R^(D4) R^(D40) L_(C251)R^(D4) R^(D41) L_(C252) R^(D4) R^(D42) L_(C253) R^(D4) R^(D43) L_(C254)R^(D4) R^(D48) L_(C255) R^(D4) R^(D49) L_(C256) R^(D4) R^(D50) L_(C257)R^(D4) R^(D54) L_(C258) R^(D4) R^(D55) L_(C259) R^(D4) R^(D58) L_(C260)R^(D4) R^(D59) L_(C261) R^(D4) R^(D78) L_(C262) R^(D4) R^(D79) L_(C263)R^(D4) R^(D81) L_(C264) R^(D4) R^(D87) L_(C265) R^(D4) R^(D88) L_(C266)R^(D4) R^(D89) L_(C267) R^(D4) R^(D93) L_(C268) R^(D4) R^(D116) L_(C269)R^(D4) R^(D117) L_(C270) R^(D4) R^(D118) L_(C271) R^(D4) R^(D119)L_(C272) R^(D4) R^(D120) L_(C273) R^(D4) R^(D133) L_(C274) R^(D4)R^(D134) L_(C275) R^(D4) R^(D135) L_(C276) R^(D4) R^(D136) L_(C277)R^(D4) R^(D143) L_(C278) R^(D4) R^(D144) L_(C279) R^(D4) R^(D145)L_(C280) R^(D4) R^(D146) L_(C281) R^(D4) R^(D147) L_(C282) R^(D4)R^(D149) L_(C283) R^(D4) R^(D151) L_(C284) R^(D4) R^(D154) L_(C285)R^(D4) R^(D155) L_(C286) R^(D4) R^(D161) L_(C287) R^(D4) R^(D175)L_(C288) R^(D9) R^(D3) L_(C289) R^(D9) R^(D5) L_(C290) R^(D9) R^(D10)L_(C291) R^(D9) R^(D17) L_(C292) R^(D9) R^(D18) L_(C293) R^(D9) R^(D20)L_(C294) R^(D9) R^(D22) L_(C295) R^(D9) R^(D37) L_(C296) R^(D9) R^(D40)L_(C297) R^(D9) R^(D41) L_(C298) R^(D9) R^(D42) L_(C299) R^(D9) R^(D43)L_(C300) R^(D9) R^(D48) L_(C301) R^(D9) R^(D49) L_(C302) R^(D9) R^(D50)L_(C303) R^(D9) R^(D54) L_(C304) R^(D9) R^(D55) L_(C305) R^(D9) R^(D58)L_(C306) R^(D9) R^(D59) L_(C307) R^(D9) R^(D78) L_(C308) R^(D9) R^(D79)L_(C309) R^(D9) R^(D81) L_(C310) R^(D9) R^(D87) L_(C311) R^(D9) R^(D88)L_(C312) R^(D9) R^(D89) L_(C313) R^(D9) R^(D93) L_(C314) R^(D9) R^(D116)L_(C315) R^(D9) R^(D117) L_(C316) R^(D9) R^(D118) L_(C317) R^(D9)R^(D119) L_(C318) R^(D9) R^(D120) L_(C319) R^(D9) R^(D133) L_(C320)R^(D9) R^(D134) L_(C321) R^(D9) R^(D135) L_(C322) R^(D9) R^(D136)L_(C323) R^(D9) R^(D143) L_(C324) R^(D9) R^(D144) L_(C325) R^(D9)R^(D145) L_(C326) R^(D9) R^(D146) L_(C327) R^(D9) R^(D147) L_(C328)R^(D9) R^(D149) L_(C329) R^(D9) R^(D151) L_(C330) R^(D9) R^(D154)L_(C331) R^(D9) R^(D155) L_(C332) R^(D9) R^(D161) L_(C333) R^(D9)R^(D175) L_(C334) R^(D10) R^(D3) L_(C335) R^(D10) R^(D5) L_(C336)R^(D10) R^(D17) L_(C337) R^(D10) R^(D18) L_(C338) R^(D10) R^(D20)L_(C339) R^(D10) R^(D22) L_(C340) R^(D10) R^(D37) L_(C341) R^(D10)R^(D40) L_(C342) R^(D10) R^(D41) L_(C343) R^(D10) R^(D42) L_(C344)R^(D10) R^(D43) L_(C345) R^(D10) R^(D48) L_(C346) R^(D10) R^(D49)L_(C347) R^(D10) R^(D50) L_(C348) R^(D10) R^(D54) L_(C349) R^(D10)R^(D55) L_(C350) R^(D10) R^(D58) L_(C351) R^(D10) R^(D59) L_(C352)R^(D10) R^(D78) L_(C353) R^(D10) R^(D79) L_(C354) R^(D10) R^(D81)L_(C355) R^(D10) R^(D87) L_(C356) R^(D10) R^(D88) L_(C357) R^(D10)R^(D89) L_(C358) R^(D10) R^(D93) L_(C359) R^(D10) R^(D116) L_(C360)R^(D10) R^(D117) L_(C361) R^(D10) R^(D118) L_(C362) R^(D10) R^(D119)L_(C363) R^(D10) R^(D120) L_(C364) R^(D10) R^(D133) L_(C365) R^(D10)R^(D134) L_(C366) R^(D10) R^(D135) L_(C367) R^(D10) R^(D136) L_(C368)R^(D10) R^(D143) L_(C369) R^(D10) R^(D144) L_(C370) R^(D10) R^(D145)L_(C371) R^(D10) R^(D146) L_(C372) R^(D10) R^(D147) L_(C373) R^(D10)R^(D149) L_(C374) R^(D10) R^(D151) L_(C375) R^(D10) R^(D154) L_(C376)R^(D10) R^(D155) L_(C377) R^(D10) R^(D161) L_(C378) R^(D10) R^(D175)L_(C379) R^(D17) R^(D3) L_(C380) R^(D17) R^(D5) L_(C381) R^(D17) R^(D18)L_(C382) R^(D17) R^(D20) L_(C383) R^(D17) R^(D22) L_(C384) R^(D17)R^(D37) L_(C385) R^(D17) R^(D40) L_(C386) R^(D17) R^(D41) L_(C387)R^(D17) R^(D42) L_(C388) R^(D17) R^(D43) L_(C389) R^(D17) R^(D48)L_(C390) R^(D17) R^(D49) L_(C391) R^(D17) R^(D50) L_(C392) R^(D17)R^(D54) L_(C393) R^(D17) R^(D55) L_(C394) R^(D17) R^(D58) L_(C395)R^(D17) R^(D59) L_(C396) R^(D17) R^(D78) L_(C397) R^(D17) R^(D79)L_(C398) R^(D17) R^(D81) L_(C399) R^(D17) R^(D87) L_(C400) R^(D17)R^(D88) L_(C401) R^(D17) R^(D89) L_(C402) R^(D17) R^(D93) L_(C403)R^(D17) R^(D116) L_(C404) R^(D17) R^(D117) L_(C405) R^(D17) R^(D118)L_(C406) R^(D17) R^(D119) L_(C407) R^(D17) R^(D120) L_(C408) R^(D17)R^(D133) L_(C409) R^(D17) R^(D134) L_(C410) R^(D17) R^(D135) L_(C411)R^(D17) R^(D136) L_(C412) R^(D17) R^(D143) L_(C413) R^(D17) R^(D144)L_(C414) R^(D17) R^(D145) L_(C415) R^(D17) R^(D146) L_(C416) R^(D17)R^(D147) L_(C417) R^(D17) R^(D149) L_(C418) R^(D17) R^(D151) L_(C419)R^(D17) R^(D154) L_(C420) R^(D17) R^(D155) L_(C421) R^(D17) R^(D161)L_(C422) R^(D17) R^(D175) L_(C423) R^(D50) R^(D3) L_(C424) R^(D50)R^(D5) L_(C425) R^(D50) R^(D18) L_(C426) R^(D50) R^(D20) L_(C427)R^(D50) R^(D22) L_(C428) R^(D50) R^(D37) L_(C429) R^(D50) R^(D40)L_(C430) R^(D50) R^(D41) L_(C431) R^(D50) R^(D42) L_(C432) R^(D50)R^(D43) L_(C433) R^(D50) R^(D48) L_(C434) R^(D50) R^(D49) L_(C435)R^(D50) R^(D54) L_(C436) R^(D50) R^(D55) L_(C437) R^(D50) R^(D58)L_(C438) R^(D50) R^(D59) L_(C439) R^(D50) R^(D78) L_(C440) R^(D50)R^(D79) L_(C441) R^(D50) R^(D81) L_(C442) R^(D50) R^(D87) L_(C443)R^(D50) R^(D88) L_(C444) R^(D50) R^(D89) L_(C445) R^(D50) R^(D93)L_(C446) R^(D50) R^(D116) L_(C447) R^(D50) R^(D117) L_(C448) R^(D50)R^(D118) L_(C449) R^(D50) R^(D119) L_(C450) R^(D50) R^(D120) L_(C451)R^(D50) R^(D133) L_(C452) R^(D50) R^(D134) L_(C453) R^(D50) R^(D135)L_(C454) R^(D50) R^(D136) L_(C455) R^(D50) R^(D143) L_(C456) R^(D50)R^(D144) L_(C457) R^(D50) R^(D145) L_(C458) R^(D50) R^(D146) L_(C459)R^(D50) R^(D147) L_(C460) R^(D50) R^(D149) L_(C461) R^(D50) R^(D151)L_(C462) R^(D50) R^(D154) L_(C463) R^(D50) R^(D155) L_(C464) R^(D50)R^(D161) L_(C465) R^(D50) R^(D175) L_(C466) R^(D55) R^(D3) L_(C467)R^(D55) R^(D5) L_(C468) R^(D55) R^(D18) L_(C469) R^(D55) R^(D20)L_(C470) R^(D55) R^(D22) L_(C471) R^(D55) R^(D37) L_(C472) R^(D55)R^(D40) L_(C473) R^(D55) R^(D41) L_(C474) R^(D55) R^(D42) L_(C475)R^(D55) R^(D43) L_(C476) R^(D55) R^(D48) L_(C477) R^(D55) R^(D49)L_(C478) R^(D55) R^(D54) L_(C479) R^(D55) R^(D58) L_(C480) R^(D55)R^(D59) L_(C481) R^(D55) R^(D78) L_(C482) R^(D55) R^(D79) L_(C483)R^(D55) R^(D81) L_(C484) R^(D55) R^(D87) L_(C485) R^(D55) R^(D88)L_(C486) R^(D55) R^(D89) L_(C487) R^(D55) R^(D93) L_(C488) R^(D55)R^(D116) L_(C489) R^(D55) R^(D117) L_(C490) R^(D55) R^(D118) L_(C491)R^(D55) R^(D119) L_(C492) R^(D55) R^(D120) L_(C493) R^(D55) R^(D133)L_(C494) R^(D55) R^(D134) L_(C495) R^(D55) R^(D135) L_(C496) R^(D55)R^(D136) L_(C497) R^(D55) R^(D143) L_(C498) R^(D55) R^(D144) L_(C499)R^(D55) R^(D145) L_(C500) R^(D55) R^(D146) L_(C501) R^(D55) R^(D147)L_(C502) R^(D55) R^(D149) L_(C503) R^(D55) R^(D151) L_(C504) R^(D55)R^(D154) L_(C505) R^(D55) R^(D155) L_(C506) R^(D55) R^(D161) L_(C507)R^(D55) R^(D175) L_(C508) R^(D116) R^(D3) L_(C509) R^(D116) R^(D5)L_(C510) R^(D116) R^(D17) L_(C511) R^(D116) R^(D18) L_(C512) R^(D116)R^(D20) L_(C513) R^(D116) R^(D22) L_(C514) R^(D116) R^(D37) L_(C515)R^(D116) R^(D40) L_(C516) R^(D116) R^(D41) L_(C517) R^(D116) R^(D42)L_(C518) R^(D116) R^(D43) L_(C519) R^(D116) R^(D48) L_(C520) R^(D116)R^(D49) L_(C521) R^(D116) R^(D54) L_(C522) R^(D116) R^(D58) L_(C523)R^(D116) R^(D59) L_(C524) R^(D116) R^(D78) L_(C525) R^(D116) R^(D79)L_(C526) R^(D116) R^(D81) L_(C527) R^(D116) R^(D87) L_(C528) R^(D116)R^(D88) L_(C529) R^(D116) R^(D89) L_(C530) R^(D116) R^(D93) L_(C531)R^(D116) R^(D117) L_(C532) R^(D116) R^(D118) L_(C533) R^(D116) R^(D119)L_(C534) R^(D116) R^(D120) L_(C535) R^(D116) R^(D133) L_(C536) R^(D116)R^(D134) L_(C537) R^(D116) R^(D135) L_(C538) R^(D116) R^(D136) L_(C539)R^(D116) R^(D143) L_(C540) R^(D116) R^(D144) L_(C541) R^(D116) R^(D145)L_(C542) R^(D116) R^(D146) L_(C543) R^(D116) R^(D147) L_(C544) R^(D116)R^(D149) L_(C545) R^(D116) R^(D151) L_(C546) R^(D116) R^(D154) L_(C547)R^(D116) R^(D155) L_(C548) R^(D116) R^(D161) L_(C549) R^(D116) R^(D175)L_(C550) R^(D143) R^(D3) L_(C551) R^(D143) R^(D5) L_(C552) R^(D143)R^(D17) L_(C553) R^(D143) R^(D18) L_(C554) R^(D143) R^(D20) L_(C555)R^(D143) R^(D22) L_(C556) R^(D143) R^(D37) L_(C557) R^(D143) R^(D40)L_(C558) R^(D143) R^(D41) L_(C559) R^(D143) R^(D42) L_(C560) R^(D143)R^(D43) L_(C561) R^(D143) R^(D48) L_(C562) R^(D143) R^(D49) L_(C563)R^(D143) R^(D54) L_(C564) R^(D143) R^(D58) L_(C565) R^(D143) R^(D59)L_(C566) R^(D143) R^(D78) L_(C567) R^(D143) R^(D79) L_(C568) R^(D143)R^(D81) L_(C569) R^(D143) R^(D87) L_(C570) R^(D143) R^(D88) L_(C571)R^(D143) R^(D89) L_(C572) R^(D143) R^(D93) L_(C573) R^(D143) R^(D116)L_(C574) R^(D143) R^(D117) L_(C575) R^(D143) R^(D118) L_(C576) R^(D143)R^(D119) L_(C577) R^(D143) R^(D120) L_(C578) R^(D143) R^(D133) L_(C579)R^(D143) R^(D134) L_(C580) R^(D143) R^(D135) L_(C581) R^(D143) R^(D136)L_(C582) R^(D143) R^(D144) L_(C583) R^(D143) R^(D145) L_(C584) R^(D143)R^(D146) L_(C585) R^(D143) R^(D147) L_(C586) R^(D143) R^(D149) L_(C587)R^(D143) R^(D151) L_(C588) R^(D143) R^(D154) L_(C589) R^(D143) R^(D155)L_(C590) R^(D143) R^(D161) L_(C591) R^(D143) R^(D175) L_(C592) R^(D144)R^(D3) L_(C593) R^(D144) R^(D5) L_(C594) R^(D144) R^(D17) L_(C595)R^(D144) R^(D18) L_(C596) R^(D144) R^(D20) L_(C597) R^(D144) R^(D22)L_(C598) R^(D144) R^(D37) L_(C599) R^(D144) R^(D40) L_(C600) R^(D144)R^(D41) L_(C601) R^(D144) R^(D42) L_(C602) R^(D144) R^(D43) L_(C603)R^(D144) R^(D48) L_(C604) R^(D144) R^(D49) L_(C605) R^(D144) R^(D54)L_(C606) R^(D144) R^(D58) L_(C607) R^(D144) R^(D59) L_(C608) R^(D144)R^(D78) L_(C609) R^(D144) R^(D79) L_(C610) R^(D144) R^(D81) L_(C611)R^(D144) R^(D87) L_(C612) R^(D144) R^(D88) L_(C613) R^(D144) R^(D89)L_(C614) R^(D144) R^(D93) L_(C615) R^(D144) R^(D116) L_(C616) R^(D144)R^(D117) L_(C617) R^(D144) R^(D118) L_(C618) R^(D144) R^(D119) L_(C619)R^(D144) R^(D120) L_(C620) R^(D144) R^(D133) L_(C621) R^(D144) R^(D134)L_(C622) R^(D144) R^(D135) L_(C623) R^(D144) R^(D136) L_(C624) R^(D144)R^(D145) L_(C625) R^(D144) R^(D146) L_(C626) R^(D144) R^(D147) L_(C627)R^(D144) R^(D149) L_(C628) R^(D144) R^(D151) L_(C629) R^(D144) R^(D154)L_(C630) R^(D144) R^(D155) L_(C631) R^(D144) R^(D161) L_(C632) R^(D144)R^(D175) L_(C633) R^(D145) R^(D3) L_(C634) R^(D145) R^(D5) L_(C635)R^(D145) R^(D17) L_(C636) R^(D145) R^(D18) L_(C637) R^(D145) R^(D20)L_(C638) R^(D145) R^(D22) L_(C639) R^(D145) R^(D37) L_(C640) R^(D145)R^(D40) L_(C641) R^(D145) R^(D41) L_(C642) R^(D145) R^(D42) L_(C643)R^(D145) R^(D43) L_(C644) R^(D145) R^(D48) L_(C645) R^(D145) R^(D49)L_(C646) R^(D145) R^(D54) L_(C647) R^(D145) R^(D58) L_(C648) R^(D145)R^(D59) L_(C649) R^(D145) R^(D78) L_(C650) R^(D145) R^(D79) L_(C651)R^(D145) R^(D81) L_(C652) R^(D145) R^(D87) L_(C653) R^(D145) R^(D88)L_(C654) R^(D145) R^(D89) L_(C655) R^(D145) R^(D93) L_(C656) R^(D145)R^(D116) L_(C657) R^(D145) R^(D117) L_(C658) R^(D145) R^(D118) L_(C659)R^(D145) R^(D119) L_(C660) R^(D145) R^(D120) L_(C661) R^(D145) R^(D133)L_(C662) R^(D145) R^(D134) L_(C663) R^(D145) R^(D135) L_(C664) R^(D145)R^(D136) L_(C665) R^(D145) R^(D146) L_(C666) R^(D145) R^(D147) L_(C667)R^(D145) R^(D149) L_(C668) R^(D145) R^(D151) L_(C669) R^(D145) R^(D154)L_(C670) R^(D145) R^(D155) L_(C671) R^(D145) R^(D161) L_(C672) R^(D145)R^(D175) L_(C673) R^(D146) R^(D3) L_(C674) R^(D146) R^(D5) L_(C675)R^(D146) R^(D17) L_(C676) R^(D146) R^(D18) L_(C677) R^(D146) R^(D20)L_(C678) R^(D146) R^(D22) L_(C679) R^(D146) R^(D37) L_(C680) R^(D146)R^(D40) L_(C681) R^(D146) R^(D41) L_(C682) R^(D146) R^(D42) L_(C683)R^(D146) R^(D43) L_(C684) R^(D146) R^(D48) L_(C685) R^(D146) R^(D49)L_(C686) R^(D146) R^(D54) L_(C687) R^(D146) R^(D58) L_(C688) R^(D146)R^(D59) L_(C689) R^(D146) R^(D78) L_(C690) R^(D146) R^(D79) L_(C691)R^(D146) R^(D81) L_(C692) R^(D146) R^(D87) L_(C693) R^(D146) R^(D88)L_(C694) R^(D146) R^(D89) L_(C695) R^(D146) R^(D93) L_(C696) R^(D146)R^(D117) L_(C697) R^(D146) R^(D118) L_(C698) R^(D146) R^(D119) L_(C699)R^(D146) R^(D120) L_(C700) R^(D146) R^(D133) L_(C701) R^(D146) R^(D134)L_(C702) R^(D146) R^(D135) L_(C703) R^(D146) R^(D136) L_(C704) R^(D146)R^(D146) L_(C705) R^(D146) R^(D147) L_(C706) R^(D146) R^(D149) L_(C707)R^(D146) R^(D151) L_(C708) R^(D146) R^(D154) L_(C709) R^(D146) R^(D155)L_(C710) R^(D146) R^(D161) L_(C711) R^(D146) R^(D175) L_(C712) R^(D133)R^(D3) L_(C713) R^(D133) R^(D5) L_(C714) R^(D133) R^(D3) L_(C715)R^(D133) R^(D18) L_(C716) R^(D133) R^(D20) L_(C717) R^(D133) R^(D22)L_(C718) R^(D133) R^(D37) L_(C719) R^(D133) R^(D40) L_(C720) R^(D133)R^(D41) L_(C721) R^(D133) R^(D42) L_(C722) R^(D133) R^(D43) L_(C723)R^(D133) R^(D48) L_(C724) R^(D133) R^(D49) L_(C725) R^(D133) R^(D54)L_(C726) R^(D133) R^(D58) L_(C727) R^(D133) R^(D59) L_(C728) R^(D133)R^(D78) L_(C729) R^(D133) R^(D79) L_(C730) R^(D133) R^(D81) L_(C731)R^(D133) R^(D87) L_(C732) R^(D133) R^(D88) L_(C733) R^(D133) R^(D89)L_(C734) R^(D133) R^(D93) L_(C735) R^(D133) R^(D117) L_(C736) R^(D133)R^(D118) L_(C737) R^(D133) R^(D119) L_(C738) R^(D133) R^(D120) L_(C739)R^(D133) R^(D133) L_(C740) R^(D133) R^(D134) L_(C741) R^(D133) R^(D135)L_(C742) R^(D133) R^(D136) L_(C743) R^(D133) R^(D146) L_(C744) R^(D133)R^(D147) L_(C745) R^(D133) R^(D149) L_(C746) R^(D133) R^(D151) L_(C747)R^(D133) R^(D154) L_(C748) R^(D133) R^(D155) L_(C749) R^(D133) R^(D161)L_(C750) R^(D133) R^(D175) L_(C751) R^(D175) R^(D3) L_(C752) R^(D175)R^(D5) L_(C753) R^(D175) R^(D18) L_(C754) R^(D175) R^(D20) L_(C755)R^(D175) R^(D22) L_(C756) R^(D175) R^(D37) L_(C757) R^(D175) R^(D40)L_(C758) R^(D175) R^(D41) L_(C759) R^(D175) R^(D42) L_(C760) R^(D175)R^(D43) L_(C761) R^(D175) R^(D48) L_(C762) R^(D175) R^(D49) L_(C763)R^(D175) R^(D54) L_(C764) R^(D175) R^(D58) L_(C765) R^(D175) R^(D59)L_(C766) R^(D175) R^(D78) L_(C767) R^(D175) R^(D79) L_(C768) R^(D175)R^(D81)wherein R^(D1) to R^(D192) have the following structures:

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, L_(B) can beselected from the group consisting of: L_(B1), L_(B2), L_(B18), L_(B28),L_(B38), L_(B108), L_(B118), L_(B122), L_(B124), L_(B126), L_(B128),L_(B130), L_(B32), L_(B134), L_(B136), L_(B138), L_(B140), L_(B142),L_(B144), L_(B156), L_(B58), L_(B160), L_(B162), L_(B164), L_(B168),L_(B172), L_(B175), L_(B204), L_(B206), L_(B214), L_(B216), L_(B218),L_(B220), L_(B222), L_(B231), L_(B233), L_(B235), L_(B237), L_(B240),L_(B242), L_(B244), L_(B246), L_(B248), L_(B250), L_(B252), L_(B254),L_(B256), L_(B258), L_(B260), L_(B262), and L_(B263). In someembodiments, L_(B) can be selected from the group consisting of: L_(B1),L_(B2), L_(B18), L_(B28), L_(B38), L_(B108), L_(B118), L_(B122),L_(B124), L_(B126), L_(B128), L_(B132), L_(B136), L_(B138), L_(B142),L_(B156), L_(B162), L_(B204), L_(B206), L_(B214), L_(B216), L_(B218),L_(B220), L_(B231), L_(B233), and L_(B237).

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, the ligandsL_(Cj-I) and L_(Cj-II) consist of only those ligands whose correspondingR¹ and R² are defined to be selected from the following structures:R^(D1), R^(D3), R^(D4), R^(D5), R^(D9), R^(D10), R^(D17), R^(D18),R^(D20), R^(D22), R^(D37), R^(D40), R^(D41), R^(D42), R^(D43), R^(D48),R^(D49), R^(D50), R^(D54), R^(D55), R^(D58), R^(D59), R^(D78), R^(D79),R^(D81), R^(D87), R^(D88), R^(D89), R^(D93), R^(D116), R^(D117),R^(D118), R^(D119), R^(D120), R^(D133), R^(D134), R^(D135), R^(D136),R^(D143), R^(D144), R^(D145), R^(D146), R^(D147), R^(D149), R^(D151),R^(D154), R^(D155), R^(D161), R^(D175), and R^(D190). In someembodiments, the ligands L_(Cj-I) and L_(Cj-II) consist of only thoseligands whose corresponding R¹ and R² are defined to be selected fromthe following structures: R^(D1), R^(D3), R^(D4), R^(D5), R^(D9),R^(D17), R^(D22), R^(D43), R^(D50), R^(D78), R^(D116), R^(D118),R^(D133), R^(D134), R^(D135), R^(D136), R^(D143), R^(D144), R^(D145),R^(D146), R^(D149), R^(D151), R^(D154), R^(D155), and R^(D190).

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, the ligand L_(C) isselected from the group consisting of:

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, the compound has aformula selected from the group consisting of Ir(L_(A))₃,Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))₂(L_(C)), andIr(L_(A))(L_(B))(L_(C)); and wherein L_(A), L_(B), and L_(C) aredifferent from each other. In some embodiments of the compound havingthe formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, thecompound has a formula of Pt(L_(A))(L_(B)); and wherein L_(A) and L_(B)can be same or different.

In some embodiments of the compound having the formula ofPt(L_(A))(L_(B)), L_(A) and L_(B) are connected to form a tetradentateligand.

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, L_(B) and L_(C) areeach independently selected from the group consisting of:

where, each Y¹ to Y¹³ is independently selected from the groupconsisting of carbon and nitrogen; Y′ is selected from the groupconsisting of B R_(e), N R_(e), P R_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) can befused or joined to form a ring; each R_(a), R_(b), R_(e), and R_(d) canindependently represent from mono to the maximum possible number ofsubstitutions, or no substitution; each R_(a), R_(b), R_(e), R_(d),R_(e) and R_(f) is independently a hydrogen or a substituent selectedfrom the group consisting of the general substituents defined herein;and any two adjacent substituents of R_(a), R_(b), R_(e), and R_(d) canbe fused or joined to form a ring or form a multidentate ligand.

In some embodiments of the compound having the formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) as defined above, L_(B) and L_(C) areeach independently selected from the group consisting of:

In some embodiments of the compound having a formula selected from thegroup consisting of Ir(L_(A))₃, Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)),Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)); and wherein L_(A),L_(B), and L_(C) are different from each other, the compound can be theCompound A_(x-F) having the formula Ir(L_(Ai-f))₃, the Compound By-Fhaving the formula Ir(L_(Ai-f))(L_(Bk))₂, or the Compound Cz-F havingthe formula Ir(L_(Ai-f))₂(L_(Cj));

where x=i, F=f, y=263i+k-263, and z=768i+j-768;

where i is an integer from 1 to 610, and f is an integer from 1 to 38,and k is an integer from 1 to 263, and j is an integer from 1 to 768;where ligands L_(Bk) have the structures L_(B1) to L_(B263) definedabove and L_(Cj) have the structures of L_(Cj-I) or L_(Cj-II) or definedabove.

In some embodiments of the compound, the compound has Formula II

where, rings C and D are each independently a 5-membered or 6-memberedcarbocyclic or heterocyclic ring; Z⁸ and Z⁹ are each independently C orN; Y¹ and Y² are each independently selected from the group consistingof a direct bond, O, and S; at least one of Y¹ and Y² is a direct bond;L¹ and L² are each independently selected from the group consisting of asingle bond, O, S, CR′R″, SiR′R″, BR′, and NR′, or is not present; atleast one of L¹ and L² is present; X¹ to X³ are each independently C orN; R^(D) and R^(E) each independently represents mono the maximumallowable substitution, or no substitution; each R′, R″, R^(C), andR^(D) is independently a hydrogen or a substituent selected from thegroup consisting of the preferred general substituents defined herein;and any two substituents may be joined or fused together to form a ring.

In some embodiments of the compound having the structure of Formula IIdefined above, ring C and ring D are both 6-membered aromatic rings. Insome embodiments, L² is O or CRR′. In some embodiments, L′ is a directbond. In some embodiments, L¹ is NR′.

In some embodiments, Z⁸ is N and Z⁹ is C. In some embodiments, Z⁸ is Cand Z⁹ is N.

In some embodiments, Y¹ and Y² are both direct bond. In someembodiments, X¹ to X³ are each C.

In some embodiments, the compound is selected from the group consistingof:

where R^(x) and R^(y) are selected from the group consisting of alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, aryl, heteroaryl, andcombinations thereof; and R^(F) and R^(G) have the same definition asR^(D) and R^(E).

C. The OLEDs and the Devices of the Present Disclosure

In another aspect, the present disclosure also provides an OLED devicecomprising a first organic layer that contains a compound as disclosedin the above compounds section of the present disclosure.

In some embodiments, the first organic layer may comprise a compoundcomprising a first ligand L_(A) of Formula I

In Formula I: ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; where the first group is selectedfrom the group consisting of:

where the asterisks in each structure indicate adjacent C atoms that areon ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; the ligand L_(A)is complexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.

In some embodiments, the organic layer may be an emissive layer and thecompound as described herein may be an emissive dopant or a non-emissivedopant.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a triphenylene containing benzo-fusedthiophene or benzo-fused furan, wherein any substituent in the host isan unfused substituent independently selected from the group consistingof C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂),CH═CH—C_(n)H_(2n+1), C≡CC_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, C_(n)H_(2n)—Ar₁, orno substitution, wherein n is from 1 to 10; and wherein Ar₁ and Ar₂ areindependently selected from the group consisting of benzene, biphenyl,naphthalene, triphenylene, carbazole, and heteroaromatic analogsthereof.

In some embodiments, the organic layer may further comprise a host,wherein host comprises at least one chemical group selected from thegroup consisting of triphenylene, carbazole, dibenzothiphene,dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole,aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments, the host may be selected from the HOST Groupconsisting of:

and combinations thereof.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a metal complex.

In some embodiments, the compound as described herein may be asensitizer; wherein the device may further comprise an acceptor; andwherein the acceptor may be selected from the group consisting offluorescent emitter, delayed fluorescence emitter, and combinationthereof

In yet another aspect, the OLED of the present disclosure may alsocomprise an emissive region containing a compound as disclosed in theabove compounds section of the present disclosure.

In some embodiments, the emissive region may comprise a compoundcomprising a first ligand L_(A) of Formula I

In Formula I: ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; where the first group is selectedfrom the group consisting of:

where the asterisks in each structure indicate adjacent C atoms that areon ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; the ligand L_(A)is complexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.

In yet another aspect, the present disclosure also provides a consumerproduct comprising an organic light-emitting device (OLED) having ananode; a cathode; and an organic layer disposed between the anode andthe cathode, wherein the organic layer may comprise a compound asdisclosed in the above compounds section of the present disclosure.

In some embodiments, the consumer product may comprise an OLED having ananode, a cathode, and an organic layer disposed between the anode andthe cathode, wherein the organic layer comprises a compound comprising afirst ligand L_(A) of Formula I

In Formula I: ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z′ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; where the first group is selectedfrom the group consisting of:

where the asterisks in each structure indicate adjacent C atoms that areon ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; the ligand L_(A)is complexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.

In some embodiments, the consumer product can be one of a flat paneldisplay, a computer monitor, a medical monitor, a television, abillboard, a light for interior or exterior illumination and/orsignaling, a heads-up display, a fully or partially transparent display,a flexible display, a laser printer, a telephone, a cell phone, tablet,a phablet, a personal digital assistant (PDA), a wearable device, alaptop computer, a digital camera, a camcorder, a viewfinder, amicro-display that is less than 2 inches diagonal, a 3-D display, avirtual reality or augmented reality display, a vehicle, a video wallcomprising multiple displays tiled together, a theater or stadiumscreen, a light therapy device, and a sign.

Generally, an OLED comprises at least one organic layer disposed betweenand electrically connected to an anode and a cathode. When a current isapplied, the anode injects holes and the cathode injects electrons intothe organic layer(s). The injected holes and electrons each migratetoward the oppositely charged electrode. When an electron and holelocalize on the same molecule, an “exciton,” which is a localizedelectron-hole pair having an excited energy state, is formed. Light isemitted when the exciton relaxes via a photoemissive mechanism. In somecases, the exciton may be localized on an excimer or an exciplex.Non-radiative mechanisms, such as thermal relaxation, may also occur,but are generally considered undesirable.

Several OLED materials and configurations are described in U.S. Pat.Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated hereinby reference in their entirety.

The initial OLEDs used emissive molecules that emitted light from theirsinglet states (“fluorescence”) as disclosed, for example, in U.S. Pat.No. 4,769,292, which is incorporated by reference in its entirety.Fluorescent emission generally occurs in a time frame of less than 10nanoseconds.

More recently, OLEDs having emissive materials that emit light fromtriplet states (“phosphorescence”) have been demonstrated. Baldo et al.,“Highly Efficient Phosphorescent Emission from OrganicElectroluminescent Devices,” Nature, vol. 395, 151-154, 1998;(“Baldo-I”) and Baldo et al., “Very high-efficiency green organiclight-emitting devices based on electrophosphorescence,” Appl. Phys.Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated byreference in their entireties. Phosphorescence is described in moredetail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporatedby reference.

FIG. 1 shows an organic light emitting device 100. The figures are notnecessarily drawn to scale. Device 100 may include a substrate 110, ananode 115, a hole injection layer 120, a hole transport layer 125, anelectron blocking layer 130, an emissive layer 135, a hole blockinglayer 140, an electron transport layer 145, an electron injection layer150, a protective layer 155, a cathode 160, and a barrier layer 170.Cathode 160 is a compound cathode having a first conductive layer 162and a second conductive layer 164. Device 100 may be fabricated bydepositing the layers described, in order. The properties and functionsof these various layers, as well as example materials, are described inmore detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which areincorporated by reference.

More examples for each of these layers are available. For example, aflexible and transparent substrate-anode combination is disclosed inU.S. Pat. No. 5,844,363, which is incorporated by reference in itsentirety. An example of a p-doped hole transport layer is m-MTDATA dopedwith F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. PatentApplication Publication No. 2003/0230980, which is incorporated byreference in its entirety. Examples of emissive and host materials aredisclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which isincorporated by reference in its entirety. An example of an n-dopedelectron transport layer is BPhen doped with Li at a molar ratio of 1:1,as disclosed in U.S. Patent Application Publication No. 2003/0230980,which is incorporated by reference in its entirety. U.S. Pat. Nos.5,703,436 and 5,707,745, which are incorporated by reference in theirentireties, disclose examples of cathodes including compound cathodeshaving a thin layer of metal such as Mg:Ag with an overlyingtransparent, electrically-conductive, sputter-deposited ITO layer. Thetheory and use of blocking layers is described in more detail in U.S.Pat. No. 6,097,147 and U.S. Patent Application Publication No.2003/0230980, which are incorporated by reference in their entireties.Examples of injection layers are provided in U.S. Patent ApplicationPublication No. 2004/0174116, which is incorporated by reference in itsentirety. A description of protective layers may be found in U.S. PatentApplication Publication No. 2004/0174116, which is incorporated byreference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210,a cathode 215, an emissive layer 220, a hole transport layer 225, and ananode 230. Device 200 may be fabricated by depositing the layersdescribed, in order. Because the most common OLED configuration has acathode disposed over the anode, and device 200 has cathode 215 disposedunder anode 230, device 200 may be referred to as an “inverted” OLED.Materials similar to those described with respect to device 100 may beused in the corresponding layers of device 200. FIG. 2 provides oneexample of how some layers may be omitted from the structure of device100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided byway of non-limiting example, and it is understood that embodiments ofthe present disclosure may be used in connection with a wide variety ofother structures. The specific materials and structures described areexemplary in nature, and other materials and structures may be used.Functional OLEDs may be achieved by combining the various layersdescribed in different ways, or layers may be omitted entirely, based ondesign, performance, and cost factors. Other layers not specificallydescribed may also be included. Materials other than those specificallydescribed may be used. Although many of the examples provided hereindescribe various layers as comprising a single material, it isunderstood that combinations of materials, such as a mixture of host anddopant, or more generally a mixture, may be used. Also, the layers mayhave various sublayers. The names given to the various layers herein arenot intended to be strictly limiting. For example, in device 200, holetransport layer 225 transports holes and injects holes into emissivelayer 220, and may be described as a hole transport layer or a holeinjection layer. In one embodiment, an OLED may be described as havingan “organic layer” disposed between a cathode and an anode. This organiclayer may comprise a single layer, or may further comprise multiplelayers of different organic materials as described, for example, withrespect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used,such as OLEDs comprised of polymeric materials (PLEDs) such as disclosedin U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated byreference in its entirety. By way of further example, OLEDs having asingle organic layer may be used. OLEDs may be stacked, for example asdescribed in U.S. Pat. No. 5,707,745 to Forrest et al, which isincorporated by reference in its entirety. The OLED structure maydeviate from the simple layered structure illustrated in FIGS. 1 and 2.For example, the substrate may include an angled reflective surface toimprove out-coupling, such as a mesa structure as described in U.S. Pat.No. 6,091,195 to Forrest et al., and/or a pit structure as described inU.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated byreference in their entireties.

Unless otherwise specified, any of the layers of the various embodimentsmay be deposited by any suitable method. For the organic layers,preferred methods include thermal evaporation, ink-jet, such asdescribed in U.S. Pat. Nos. 6,013,982 and 6,087,196, which areincorporated by reference in their entireties, organic vapor phasedeposition (OVPD), such as described in U.S. Pat. No. 6,337,102 toForrest et al., which is incorporated by reference in its entirety, anddeposition by organic vapor jet printing (OVJP), such as described inU.S. Pat. No. 7,431,968, which is incorporated by reference in itsentirety. Other suitable deposition methods include spin coating andother solution based processes. Solution based processes are preferablycarried out in nitrogen or an inert atmosphere. For the other layers,preferred methods include thermal evaporation. Preferred patterningmethods include deposition through a mask, cold welding such asdescribed in U.S. Pat. Nos. 6,294,398 and 6,468,819, which areincorporated by reference in their entireties, and patterning associatedwith some of the deposition methods such as ink-jet and organic vaporjet printing (OVJP). Other methods may also be used. The materials to bedeposited may be modified to make them compatible with a particulardeposition method. For example, substituents such as alkyl and arylgroups, branched or unbranched, and preferably containing at least 3carbons, may be used in small molecules to enhance their ability toundergo solution processing. Substituents having 20 carbons or more maybe used, and 3-20 carbons are a preferred range. Materials withasymmetric structures may have better solution processability than thosehaving symmetric structures, because asymmetric materials may have alower tendency to recrystallize. Dendrimer substituents may be used toenhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the presentdisclosure may further optionally comprise a barrier layer. One purposeof the barrier layer is to protect the electrodes and organic layersfrom damaging exposure to harmful species in the environment includingmoisture, vapor and/or gases, etc. The barrier layer may be depositedover, under or next to a substrate, an electrode, or over any otherparts of a device including an edge. The barrier layer may comprise asingle layer, or multiple layers. The barrier layer may be formed byvarious known chemical vapor deposition techniques and may includecompositions having a single phase as well as compositions havingmultiple phases. Any suitable material or combination of materials maybe used for the barrier layer. The barrier layer may incorporate aninorganic or an organic compound or both. The preferred barrier layercomprises a mixture of a polymeric material and a non-polymeric materialas described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos.PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporatedby reference in their entireties. To be considered a “mixture”, theaforesaid polymeric and non-polymeric materials comprising the barrierlayer should be deposited under the same reaction conditions and/or atthe same time. The weight ratio of polymeric to non-polymeric materialmay be in the range of 95:5 to 5:95. The polymeric material and thenon-polymeric material may be created from the same precursor material.In one example, the mixture of a polymeric material and a non-polymericmaterial consists essentially of polymeric silicon and inorganicsilicon.

Devices fabricated in accordance with embodiments of the presentdisclosure can be incorporated into a wide variety of electroniccomponent modules (or units) that can be incorporated into a variety ofelectronic products or intermediate components. Examples of suchelectronic products or intermediate components include display screens,lighting devices such as discrete light source devices or lightingpanels, etc. that can be utilized by the end-user product manufacturers.Such electronic component modules can optionally include the drivingelectronics and/or power source(s). Devices fabricated in accordancewith embodiments of the present disclosure can be incorporated into awide variety of consumer products that have one or more of theelectronic component modules (or units) incorporated therein. A consumerproduct comprising an OLED that includes the compound of the presentdisclosure in the organic layer in the OLED is disclosed. Such consumerproducts would include any kind of products that include one or morelight source(s) and/or one or more of some type of visual displays.

Some examples of such consumer products include flat panel displays,curved displays, computer monitors, medical monitors, televisions,billboards, lights for interior or exterior illumination and/orsignaling, heads-up displays, fully or partially transparent displays,flexible displays, rollable displays, foldable displays, stretchabledisplays, laser printers, telephones, mobile phones, tablets, phablets,personal digital assistants (PDAs), wearable devices, laptop computers,digital cameras, camcorders, viewfinders, micro-displays (displays thatare less than 2 inches diagonal), 3-D displays, virtual reality oraugmented reality displays, vehicles, video walls comprising multipledisplays tiled together, theater or stadium screen, a light therapydevice, and a sign. Various control mechanisms may be used to controldevices fabricated in accordance with the present disclosure, includingpassive matrix and active matrix. Many of the devices are intended foruse in a temperature range comfortable to humans, such as 18 degrees C.to 30 degrees C., and more preferably at room temperature (20-25° C.),but could be used outside this temperature range, for example, from −40degree C. to +80° C.

More details on OLEDs, and the definitions described above, can be foundin U.S. Pat. No. 7,279,704, which is incorporated herein by reference inits entirety.

The materials and structures described herein may have applications indevices other than OLEDs. For example, other optoelectronic devices suchas organic solar cells and organic photodetectors may employ thematerials and structures. More generally, organic devices, such asorganic transistors, may employ the materials and structures.

In some embodiments, the OLED has one or more characteristics selectedfrom the group consisting of being flexible, being rollable, beingfoldable, being stretchable, and being curved. In some embodiments, theOLED is transparent or semi-transparent. In some embodiments, the OLEDfurther comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising adelayed fluorescent emitter. In some embodiments, the OLED comprises aRGB pixel arrangement or white plus color filter pixel arrangement. Insome embodiments, the OLED is a mobile device, a hand held device, or awearable device. In some embodiments, the OLED is a display panel havingless than 10 inch diagonal or 50 square inch area. In some embodiments,the OLED is a display panel having at least 10 inch diagonal or 50square inch area. In some embodiments, the OLED is a lighting panel.

In some embodiments, the compound can be an emissive dopant. In someembodiments, the compound can produce emissions via phosphorescence,fluorescence, thermally activated delayed fluorescence, i.e., TADF (alsoreferred to as E-type delayed fluorescence; see, e.g., U.S. applicationSer. No. 15/700,352, which is hereby incorporated by reference in itsentirety), triplet-triplet annihilation, or combinations of theseprocesses. In some embodiments, the emissive dopant can be a racemicmixture, or can be enriched in one enantiomer. In some embodiments, thecompound can be homoleptic (each ligand is the same). In someembodiments, the compound can be heteroleptic (at least one ligand isdifferent from others). When there are more than one ligand coordinatedto a metal, the ligands can all be the same in some embodiments. In someother embodiments, at least one ligand is different from the otherligands. In some embodiments, every ligand can be different from eachother. This is also true in embodiments where a ligand being coordinatedto a metal can be linked with other ligands being coordinated to thatmetal to form a tridentate, tetradentate, pentadentate, or hexadentateligands. Thus, where the coordinating ligands are being linked together,all of the ligands can be the same in some embodiments, and at least oneof the ligands being linked can be different from the other ligand(s) insome other embodiments.

In some embodiments, the compound can be used as a phosphorescentsensitizer in an OLED where one or multiple layers in the OLED containsan acceptor in the form of one or more fluorescent and/or delayedfluorescence emitters. In some embodiments, the compound can be used asone component of an exciplex to be used as a sensitizer. As aphosphorescent sensitizer, the compound must be capable of energytransfer to the acceptor and the acceptor will emit the energy orfurther transfer energy to a final emitter. The acceptor concentrationscan range from 0.001% to 100%. The acceptor could be in either the samelayer as the phosphorescent sensitizer or in one or more differentlayers. In some embodiments, the acceptor is a TADF emitter. In someembodiments, the acceptor is a fluorescent emitter. In some embodiments,the emission can arise from any or all of the sensitizer, acceptor, andfinal emitter

According to another aspect, a formulation comprising the compounddescribed herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of aconsumer product, an electronic component module, and a lighting panel.The organic layer can be an emissive layer and the compound can be anemissive dopant in some embodiments, while the compound can be anon-emissive dopant in other embodiments.

In yet another aspect of the present disclosure, a formulation thatcomprises the novel compound disclosed herein is described. Theformulation can include one or more components selected from the groupconsisting of a solvent, a host, a hole injection material, holetransport material, electron blocking material, hole blocking material,and an electron transport material, disclosed herein.

The present disclosure encompasses any chemical structure comprising thenovel compound of the present disclosure, or a monovalent or polyvalentvariant thereof. In other words, the inventive compound, or a monovalentor polyvalent variant thereof, can be a part of a larger chemicalstructure. Such chemical structure can be selected from the groupconsisting of a monomer, a polymer, a macromolecule, and a supramolecule(also known as supermolecule). As used herein, a “monovalent variant ofa compound” refers to a moiety that is identical to the compound exceptthat one hydrogen has been removed and replaced with a bond to the restof the chemical structure. As used herein, a “polyvalent variant of acompound” refers to a moiety that is identical to the compound exceptthat more than one hydrogen has been removed and replaced with a bond orbonds to the rest of the chemical structure. In the instance of asupramolecule, the inventive compound can also be incorporated into thesupramolecule complex without covalent bonds.

D. Combination of the Compounds of the Present Disclosure with OtherMaterials

The materials described herein as useful for a particular layer in anorganic light emitting device may be used in combination with a widevariety of other materials present in the device. For example, emissivedopants disclosed herein may be used in conjunction with a wide varietyof hosts, transport layers, blocking layers, injection layers,electrodes and other layers that may be present. The materials describedor referred to below are non-limiting examples of materials that may beuseful in combination with the compounds disclosed herein, and one ofskill in the art can readily consult the literature to identify othermaterials that may be useful in combination.

a) Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants tosubstantially alter its density of charge carriers, which will in turnalter its conductivity. The conductivity is increased by generatingcharge carriers in the matrix material, and depending on the type ofdopant, a change in the Fermi level of the semiconductor may also beachieved. Hole-transporting layer can be doped by p-type conductivitydopants and n-type conductivity dopants are used in theelectron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:EP01617493, EP01968131, EP2020694, EP2684932, US20050139810,US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455,WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804,US20150123047, and US2012146012.

b) HIL/HTL:

A hole injecting/transporting material to be used in the presentdisclosure is not particularly limited, and any compound may be used aslong as the compound is typically used as a hole injecting/transportingmaterial. Examples of the material include, but are not limited to: aphthalocyanine or porphyrin derivative; an aromatic amine derivative; anindolocarbazole derivative; a polymer containing fluorohydrocarbon; apolymer with conductivity dopants; a conducting polymer, such asPEDOT/PSS; a self-assembly monomer derived from compounds such asphosphonic acid and silane derivatives; a metal oxide derivative, suchas MoO_(x); a p-type semiconducting organic compound, such as1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and across-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, butnot limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatichydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl,triphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each Ar may beunsubstituted or may be substituted by a substituent selected from thegroup consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the groupconsisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH)or N; Z¹⁰¹ is NAr¹, O, or S; AO has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are notlimited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40;(Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independentlyselected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is aninteger value from 1 to the maximum number of ligands that may beattached to the metal; and k′+k″ is the maximum number of ligands thatmay be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In anotheraspect, carbene ligand. In another aspect, Met is selected from Ir, Pt,Os, and Zn. In a further aspect, the metal complex has a smallestoxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used inan OLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334,EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701,EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765,JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473,TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053,US20050123751, US20060182993, US20060240279, US20070145888,US20070181874, US20070278938, US20080014464, US20080091025,US20080106190, US20080124572, US20080145707, US20080220265,US20080233434, US20080303417, US2008107919, US20090115320,US20090167161, US2009066235, US2011007385, US20110163302, US2011240968,US2011278551, US2012205642, US2013241401, US20140117329, US2014183517,U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550,WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006,WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577,WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937,WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

c) EBL:

An electron blocking layer (EBL) may be used to reduce the number ofelectrons and/or excitons that leave the emissive layer. The presence ofsuch a blocking layer in a device may result in substantially higherefficiencies, and/or longer lifetime, as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the EBLmaterial has a higher LUMO (closer to the vacuum level) and/or highertriplet energy than the emitter closest to the EBL interface. In someembodiments, the EBL material has a higher LUMO (closer to the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the EBL interface. In one aspect, the compound used in EBLcontains the same molecule or the same functional groups used as one ofthe hosts described below.

d) Hosts:

The light emitting layer of the organic EL device of the presentdisclosure preferably contains at least a metal complex as lightemitting material, and may contain a host material using the metalcomplex as a dopant material. Examples of the host material are notparticularly limited, and any metal complexes or organic compounds maybe used as long as the triplet energy of the host is larger than that ofthe dopant. Any host material may be used with any dopant so long as thetriplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have thefollowing general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹ is an anotherligand; k′ is an integer value from 1 to the maximum number of ligandsthat may be attached to the metal; and k′+k″ is the maximum number ofligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms Oand N.

In another aspect, Met is selected from Ir and Pt. In a further aspect,(Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

In one aspect, the host compound contains at least one of the followinggroups selected from the group consisting of aromatic hydrocarbon cycliccompounds such as benzene, biphenyl, triphenyl, triphenylene,tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each option withineach group may be unsubstituted or may be substituted by a substituentselected from the group consisting of deuterium, halogen, alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile,sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the followinggroups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, and when it is aryl or heteroaryl, it has thesimilar definition as Ar's mentioned above. k is an integer from 0 to 20or 1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (includingCH) or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: EP2034538,EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644,KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919,US20060280965, US20090017330, US20090030202, US20090167162,US20090302743, US20090309488, US20100012931, US20100084966,US20100187984, US2010187984, US2012075273, US2012126221, US2013009543,US2013105787, US2013175519, US2014001446, US20140183503, US20140225088,US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207,WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754,WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778,WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423,WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649,WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,US20170263869, US20160163995, U.S. Pat. No. 9,466,803,

e) Additional Emitters:

One or more additional emitter dopants may be used in conjunction withthe compound of the present disclosure. Examples of the additionalemitter dopants are not particularly limited, and any compounds may beused as long as the compounds are typically used as emitter materials.Examples of suitable emitter materials include, but are not limited to,compounds which can produce emissions via phosphorescence, fluorescence,thermally activated delayed fluorescence, i.e., TADF (also referred toas E-type delayed fluorescence), triplet-triplet annihilation, orcombinations of these processes.

Non-limiting examples of the emitter materials that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526,EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907,EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652,KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599,U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526,US20030072964, US20030138657, US20050123788, US20050244673,US2005123791, US2005260449, US20060008670, US20060065890, US20060127696,US20060134459, US20060134462, US20060202194, US20060251923,US20070034863, US20070087321, US20070103060, US20070111026,US20070190359, US20070231600, US2007034863, US2007104979, US2007104980,US2007138437, US2007224450, US2007278936, US20080020237, US20080233410,US20080261076, US20080297033, US200805851, US2008161567, US2008210930,US20090039776, US20090108737, US20090115322, US20090179555,US2009085476, US2009104472, US20100090591, US20100148663, US20100244004,US20100295032, US2010102716, US2010105902, US2010244004, US2010270916,US20110057559, US20110108822, US20110204333, US2011215710, US2011227049,US2011285275, US2012292601, US20130146848, US2013033172, US2013165653,US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos.6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469,6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228,7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586,8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970,WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373,WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842,WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731,WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491,WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471,WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977,WO2014038456, WO2014112450.

f) HBL:

A hole blocking layer (HBL) may be used to reduce the number of holesand/or excitons that leave the emissive layer. The presence of such ablocking layer in a device may result in substantially higherefficiencies and/or longer lifetime as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the HBLmaterial has a lower HOMO (further from the vacuum level) and/or highertriplet energy than the emitter closest to the HBL interface. In someembodiments, the HBL material has a lower HOMO (further from the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or thesame functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of thefollowing groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is another ligand, k′ is aninteger from 1 to 3.

g) ETL:

Electron transport layer (ETL) may include a material capable oftransporting electrons. Electron transport layer may be intrinsic(undoped), or doped. Doping may be used to enhance conductivity.Examples of the ETL material are not particularly limited, and any metalcomplexes or organic compounds may be used as long as they are typicallyused to transport electrons.

In one aspect, compound used in ETL contains at least one of thefollowing groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, when it is aryl or heteroaryl, it has the similardefinition as Ar's mentioned above. Ar¹ to Ar³ has the similardefinition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but notlimit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinatedto atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer valuefrom 1 to the maximum number of ligands that may be attached to themetal.

Non-limiting examples of the ETL materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: CN103508940,EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918,JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977,US2007018155, US20090101870, US20090115316, US20090140637,US20090179554, US2009218940, US2010108990, US2011156017, US2011210320,US2012193612, US2012214993, US2014014925, US2014014927, US20140284580,U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263,WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373,WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

h) Charge generation layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in theperformance, which is composed of an n-doped layer and a p-doped layerfor injection of electrons and holes, respectively. Electrons and holesare supplied from the CGL and electrodes. The consumed electrons andholes in the CGL are refilled by the electrons and holes injected fromthe cathode and anode, respectively; then, the bipolar currents reach asteady state gradually. Typical CGL materials include n and pconductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device,the hydrogen atoms can be partially or fully deuterated. Thus, anyspecifically listed substituent, such as, without limitation, methyl,phenyl, pyridyl, etc. may be undeuterated, partially deuterated, andfully deuterated versions thereof. Similarly, classes of substituentssuch as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc.also may be undeuterated, partially deuterated, and fully deuteratedversions thereof.

Synthesis of materials

To a solution of 5,6-dibromobenzo[c][1,2,5]thiadiazole (25.00 g, 85mmol) in toluene (200 mL), benzophenone imine (38.50 ml, 230 mmol),BINAP (5.30 g, 8.50 mmol) and sodium tert-butoxide (20.43 g, 213 mmol)were added. This mixture was degassed under nitrogen for 15 minutes.Palladium (II) acetate (0.96 g, 4.25 mmol) was then added. After furtherdegassing for 10 minutes, the reaction mixture was stirred at 110° C.for 7 hours. Upon completion of the reaction, the reaction mixture wascooled to room temperature and concentrated in vacuo. The resultingcrude was re-dissolved in EtOAc (1000 mL) and extracted with H₂O (600mL). The aqueous phase was re-extracted with further EtOAc (3×1000 mL).All the organic phases were combined, washed with brine, dried withMgSO₄, filtered and then concentrated in vacuo in order to isolate crudeN,N′-(benzo[c][1,2,5]thiadiazole-5,6-diyl)bis(1,1-diphenylmethanimine)(57.62 g, 103 mmol, >99%) as a brown solid.

To a solution of crudeN,N′-(benzo[c][1,2,5]thiadiazole-5,6-diyl)bis(1,1-diphenylmethanimine)(57.62 g, 85 mmol) in THF (600 mL), concentrated HCl (18.10 mL, 596mmol) was added. This mixture was left to stir at 35° C. for 16 hours.After this time, the reaction mixture was cooled to room temperature andconcentrated in vacuo. This was re-dissolved in EtOAc (600 mL) andextracted with NaHCO₃ (200 mL) sat. aq. sol. The aqueous phase wasre-extracted with further EtOAc (3×300 mL). All the organic phases werecombined, washed with brine, dried with MgSO₄, filtered and thenconcentrated in vacuo in order to isolate crudebenzo[c][1,2,5]thiadiazole-5,6-diamine as a black oil (57.20 g).

A mixture of containing4-(tert-butyl)naphthalen-2-yltrifluoromethanesulfonate (12.50 g, 37.60mmol), copper(I) iodide (0.72 g, 3.76 mmol), Pd(PPh₃)₂Cl₂ (1.32 g, 1.88mmol) and triethylamine anhydrous (15.73 mL, 113 mmol) in DMF (175 mL)was degassed under N₂ for 10 minutes. To this, prop-1-yne (4% in DMF)(94 mL, 94 mmol) was added. This was left to stir at room temperaturefor 18 hours. After this time, the reaction mixture was concentrated invacuo. This was purified by flash chromatography to isolate1-(tert-butyl)-3-(prop-1-yn-1-yl)naphthalene (8.67 g, 35.2 mmol, 87%yield) as a yellow oil.

To a mixture containing 1-(tert-butyl)-3-(prop-1-yn-1-yl)naphthalene(7.83 g, 35.2 mmol) and phenyl-13-iodanediyl diacetate (34.0 g, 106mmol) in DCM (140 ml) and H₂O (28 ml), ruthenium(III) chloride (0.730 g,3.52 mmol) was added. This was left to stir at 30° C. for 18 hours. Uponreaction completion, the reaction mixture was cooled to room temperatureand concentrated in vacuo. This was purified by flash chromatography toisolate 1-(4-(tert-butyl)naphthalen-2-yl)propane-1,2-dione (5.06 g,19.84 mmol, 56.3% yield) as a yellow oil.

To a mixture of 1-(4-(tert-butyl)naphthalen-2-yl)propane-1,2-dione (5.06g, 19.90 mmol) in EtOH (135 ml), benzo[c][1,2,5]thiadiazole-5,6-diamine(3.97 g, 23.87 mmol) was added. This mixture was left to stir at 40° C.for 21 hours. Upon completion of the reaction, the reaction mixture wascooled to room temperature and concentrated in vacuo. This was purifiedby flash chromatography to isolate6-(4-(tert-butypnaphthalen-2-yl)-7-methyl-[1,2,5]thiadiazolo[3,4-g]quinoxaline,as a yellow solid.

The Inventive compound I, Ir(L_(A6-6))₂LC₁₇, can be made in conventionaltwo-step process. Ir dimer can be made by refluxing6-(4-(tert-butyl)naphthalen-2-yl)-7-methyl-[1,2,5]thiadiazolo[3,4-g]quinoxalineand IrCl3 in a mixture of 2-ethoxyethanol and water, which then reactswith 3,7-diethylnonane-4,6-dione and potassium carbonate to give theinventive compound.

The energy of the lowest triplet excited state (T₁) of the inventivecompounds is estimated by theoretical calculation. DFT calculations wereperformed to determine S₁, T₁, HOMO, and LUMO of the compounds. The datawas gathered using the program Gaussian16. Geometries were optimizedusing B3LYP functional and CEP-31G basis set. Excited state energieswere computed by TDDFT at the optimized ground state geometries. T₁ ofthe inventive compound Ir(L_(A6-6))₂L_(C17) was calculated to be 1783nm. As would be understood by one of ordinary skill in the art, thecompound will emit light in the NIR region. As demonstrated herein, theinventive compounds are useful materials as emitters in OLED devices toimprove device performance.

The calculations obtained with the above-identified DFT functional setand basis set are theoretical. Computational composite protocols, suchas the Gaussian09 with B3LYP and CEP-31G protocol used herein, rely onthe assumption that electronic effects are additive and, therefore,larger basis sets can be used to extrapolate to the complete basis set(CBS) limit. However, when the goal of a study is to understandvariations in HOMO, LUMO, S₁, T₁, bond dissociation energies, etc. overa series of structurally-related compounds, the additive effects areexpected to be similar. Accordingly, while absolute errors from usingthe B3LYP may be significant compared to other computational methods,the relative differences between the HOMO, LUMO, S₁, T₁, and bonddissociation energy values calculated with B3LYP protocol are expectedto reproduce experiment quite well. See, e.g., Hong et al., Chem. Mater.2016, 28, 5791-98, 5792-93 and Supplemental Information (discussing thereliability of DFT calculations in the context of OLED materials).Moreover, with respect to iridium or platinum complexes that are usefulin the OLED art, the data obtained from DFT calculations correlates verywell to actual experimental data. See Tavasli et al., J. Mater. Chem.2012, 22, 6419-29, 6422 (Table 3) (showing DFT calculations closelycorrelating with actual data for a variety of emissive complexes);Morello, G. R., J. Mol. Model. 2017, 23:174 (studying of a variety ofDFT functional sets and basis sets and concluding the combination ofB3LYP and CEP-31G is particularly accurate for emissive complexes).

It is understood that the various embodiments described herein are byway of example only and are not intended to limit the scope of theinvention. For example, many of the materials and structures describedherein may be substituted with other materials and structures withoutdeviating from the spirit of the invention. The present invention asclaimed may therefore include variations from the particular examplesand preferred embodiments described herein, as will be apparent to oneof skill in the art. It is understood that various theories as to whythe invention works are not intended to be limiting.

1. A compound comprising a first ligand L_(A) of Formula I

wherein, ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; wherein the first group isselected from the group consisting of:

wherein the asterisks in each structure indicate adjacent C atoms thatare on ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, boryl, and combinations thereof; the ligand L_(A) iscomplexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.
 2. The compound of claim 1, wherein each R, R^(A),R^(B), and R^(C) is independently a hydrogen or a substituent selectedfrom the group consisting of deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl,and combinations thereof.
 3. The compound of claim 1, wherein Z¹ and Z⁴are N, and Z² and Z³ are C.
 4. (canceled)
 5. The compound of claim 1,wherein ring A is selected from the group consisting of benzene,pyridine, pyrazine, pyridazine, triazole, pyrrole, pyrroledione,oxadiazole, thiadiazole, and selenadiazole.
 6. The compound of claim 1,wherein ring B is a 6-membered aromatic ring.
 7. The compound of claim1, wherein two adjacent R^(B) substituents join together to form a6-membered aromatic ring fused to ring B.
 8. (canceled)
 9. The compoundof claim 1, wherein ring A is a benzene ring, and two adjacent R^(A)substituents are joined together to form a ring fused to ring A, whereinthe two adjacent R^(A) substituents are independently selected from thegroup consisting of:


10. The compound of claim 1, wherein M is selected from the groupconsisting of Os, Ir, Pd, Pt, Cu, Ag, and Au.
 11. (canceled)
 12. Thecompound of claim 1, wherein M is coordinated to a substituted orunsubstituted acetylacetonate ligand.
 13. The compound of claim 1,wherein the first ligand L_(A) is selected from the group consisting of:

and wherein Z⁶ and Z⁷ are each independently C or N.
 14. The compound ofclaim 1, wherein the first ligand L_(A) is selected from the groupconsisting of: L_(Ai-1), wherein i=1 to 200, that are based on Formula 1

L_(Ai-2), wherein i=1 to 200, that are based on Formula 2

L_(Ai-3), wherein i=1 to 200, that are based on Formula 3

L_(Ai-4), wherein i=1 to 200, that are based on Formula 4

L_(Ai-5), wherein i=1 to 200, that are based on Formula 5

L_(Ai-6), wherein i=1 to 200, that are based on Formula 6

L_(Ai-7), wherein i=1 to 200, that are based on Formula 7

L_(Ai-8), wherein i=1 to 200, that are based on Formula 8

L_(Ai-9), wherein i=1 to 200, that are based on Formula 9

L_(Ai-10), wherein i=1 to 200, that are based on Formula 10

L_(Ai-11), wherein i=1 to 200, that are based on Formula 11

L_(Ai-12), wherein i=1 to 200, that are based on Formula 12

L_(Ai-13), wherein i=1 to 200, that are based on Formula 13

L_(Ai-14), wherein i=1 to 200, that are based on Formula 14

L_(Ai-15), wherein i=1 to 200, that are based on Formula 15

L_(Ai-16), wherein i=1 to 200, that are based on Formula 16

L_(Ai-17), wherein i=1 to 200, that are based on Formula 17

L_(Ai-18), wherein i=1 to 200, that are based on Formula 18

L_(Ai-19), wherein i=1 to 200, that are based on Formula 19

wherein R^(D) and G are defined as follows: L_(Ai) R^(D) G L_(A1) R¹ G¹L_(A2) R¹ G² L_(A3) R¹ G³ L_(A4) R¹ G⁴ L_(A5) R¹ G⁵ L_(A6) R¹ G⁶ L_(A7)R¹ G⁷ L_(A8) R¹ G⁸ L_(A9) R¹ G⁹ L_(A10) R¹ G¹⁰ L_(A11) R² G¹ L_(A12) R²G² L_(A13) R² G³ L_(A14) R² G⁴ L_(A15) R² G⁵ L_(A16) R² G⁶ L_(A17) R² G⁷L_(A18) R² G⁸ L_(A19) R² G⁹ L_(A20) R² G¹⁰ L_(A21) R³ G¹ L_(A22) R³ G²L_(A23) R³ G³ L_(A24) R³ G⁴ L_(A25) R³ G⁵ L_(A26) R³ G⁶ L_(A27) R³ G⁷L_(A28) R³ G⁸ L_(A29) R³ G⁹ L_(A30) R³ G¹⁰ L_(A31) R⁴ G¹ L_(A32) R⁴ G²L_(A33) R⁴ G³ L_(A34) R⁴ G⁴ L_(A35) R⁴ G⁵ L_(A36) R⁴ G⁶ L_(A37) R⁴ G⁷L_(A38) R⁴ G⁸ L_(A39) R⁴ G⁹ L_(A40) R⁴ G¹⁰ L_(A41) R⁵ G¹ L_(A42) R⁵ G²L_(A43) R⁵ G³ L_(A44) R⁵ G⁴ L_(A45) R⁵ G⁵ L_(A46) R⁵ G⁶ L_(A47) R⁵ G⁷L_(A48) R⁵ G⁸ L_(A49) R⁵ G⁹ L_(A50) R⁵ G¹⁰ L_(A51) R⁶ G¹ L_(A52) R⁶ G²L_(A53) R⁶ G³ L_(A54) R⁶ G⁴ L_(A55) R⁶ G⁵ L_(A56) R⁶ G⁶ L_(A57) R⁶ G⁷L_(A58) R⁶ G⁸ L_(A59) R⁶ G⁹ L_(A60) R⁶ G¹⁰ L_(A61) R⁷ G¹ L_(A62) R⁷ G²L_(A63) R⁷ G³ L_(A64) R⁷ G⁴ L_(A65) R⁷ G⁵ L_(A66) R⁷ G⁶ L_(A67) R⁷ G⁷L_(A68) R⁷ G⁸ L_(A69) R⁷ G⁹ L_(A70) R⁷ G¹⁰ L_(A71) R⁸ G¹ L_(A72) R⁸ G²L_(A73) R⁸ G³ L_(A24) R⁸ G⁴ L_(A75) R⁸ G⁵ L_(A76) R⁸ G⁶ L_(A77) R⁸ G⁷L_(A78) R⁸ G⁸ L_(A79) R⁸ G⁹ L_(A80) R⁸ G¹⁰ L_(A81) R⁹ G¹ L_(A82) R⁹ G²L_(A83) R⁹ G³ L_(A84) R⁹ G⁴ L_(A85) R⁹ G⁵ L_(A86) R⁹ G⁶ L_(A87) R⁹ G⁷L_(A88) R⁹ G⁸ L_(A89) R⁹ G⁹ L_(A90) R⁹ G¹⁰ L_(A91) R¹⁰ G¹ L_(A92) R¹⁰ G²L_(A93) R¹⁰ G³ L_(A94) R¹⁰ G⁴ L_(A95) R¹⁰ G⁵ L_(A96) R¹⁰ G⁶ L_(A97) R¹⁰G⁷ L_(A98) R¹⁰ G⁸ L_(A99) R¹⁰ G⁹ L_(A100) R¹⁰ G¹⁰ L_(A101) R¹¹ G¹L_(A102) R¹¹ G² L_(A103) R¹¹ G³ L_(A104) R¹¹ G⁴ L_(A105) R¹¹ G⁵ L_(A106)R¹¹ G⁶ L_(A107) R¹¹ G⁷ L_(A108) R¹¹ G⁸ L_(A109) R¹¹ G⁹ L_(A110) R¹¹ G¹⁰L_(A111) R¹² G¹ L_(A112) R¹² G² L_(A113) R¹² G³ L_(A114) R¹² G⁴ L_(A115)R¹² G⁵ L_(A116) R¹² G⁶ L_(A117) R¹² G⁷ L_(A118) R¹² G⁸ L_(A119) R¹² G⁹L_(A120) R¹² G¹⁰ L_(A121) R¹³ G¹ L_(A122) R¹³ G² L_(A123) R¹³ G³L_(A124) R¹³ G⁴ L_(A125) R¹³ G⁵ L_(A126) R¹³ G⁶ L_(A127) R¹³ G⁷ L_(A128)R¹³ G⁸ L_(A129) R¹³ G⁹ L_(A130) R¹³ G¹⁰ L_(A131) R¹⁴ G¹ L_(A132) R¹⁴ G²L_(A133) R¹⁴ G³ L_(A134) R¹⁴ G⁴ L_(A135) R¹⁴ G⁵ L_(A136) R¹⁴ G⁶ L_(A137)R¹⁴ G⁷ L_(A138) R¹⁴ G⁸ L_(A139) R¹⁴ G⁹ L_(A140) R¹⁴ G¹⁰ L_(A141) R¹⁵ G¹L_(A142) R¹⁵ G² L_(A143) R¹⁵ G³ L_(A144) R¹⁵ G⁴ L_(A145) R¹⁵ G⁵ L_(A146)R¹⁵ G⁶ L_(A147) R¹⁵ G⁷ L_(A148) R¹⁵ G⁸ L_(A149) R¹⁵ G⁹ L_(A150) R¹⁵ G¹⁰L_(A151) R¹⁶ G¹ L_(A152) R¹⁶ G² L_(A153) R¹⁶ G³ L_(A154) R¹⁶ G⁴ L_(A155)R¹⁶ G⁵ L_(A156) R¹⁶ G⁶ L_(A157) R¹⁶ G⁷ L_(A158) R¹⁶ G⁸ L_(A159) R¹⁶ G⁹L_(A160) R¹⁶ G¹⁰ L_(A161) R¹⁷ G¹ L_(A162) R¹⁷ G² L_(A163) R¹⁷ G³L_(A164) R¹⁷ G⁴ L_(A165) R¹⁷ G⁵ L_(A166) R¹⁷ G⁶ L_(A167) R¹⁷ G⁷ L_(A168)R¹⁷ G⁸ L_(A169) R¹⁷ G⁹ L_(A170) R¹⁷ G¹⁰ L_(A171) R¹⁸ G¹ L_(A172) R¹⁸ G²L_(A173) R¹⁸ G³ L_(A174) R¹⁸ G⁴ L_(A175) R¹⁸ G⁵ L_(A176) R¹⁸ G⁶ L_(A177)R¹⁸ G⁷ L_(A178) R¹⁸ G⁸ L_(A179) R¹⁸ G⁹ L_(A180) R¹⁸ G¹⁰ L_(A181) R¹⁹ G¹L_(A182) R¹⁹ G² L_(A183) R¹⁹ G³ L_(A184) R¹⁹ G⁴ L_(A185) R¹⁹ G⁵ L_(A186)R¹⁹ G⁶ L_(A187) R¹⁹ G⁷ L_(A188) R¹⁹ G⁸ L_(A189) R¹⁹ G⁹ L_(A190) R¹⁹ G¹⁰L_(A191) R²⁰ G¹ L_(A192) R²⁰ G² L_(A193) R²⁰ G³ L_(A194) R²⁰ G⁴ L_(A195)R²⁰ G⁵ L_(A196) R²⁰ G⁶ L_(A197) R²⁰ G⁷ L_(A198) R²⁰ G⁸ L_(A199) R²⁰ G⁹L_(A200) R²⁰ G¹⁰

L_(Ai-20), wherein i=201 to 600, that are based on Formula 20

L_(Ai-21), wherein i=201 to 600, that are based on Formula 21

L_(Ai-22), wherein i=201 to 600, that are based on Formula 22

L_(Ai-23), wherein i=201 to 600, that are based on Formula 23

L_(Ai-24), wherein i=201 to 600, that are based on Formula 24

L_(Ai-25), wherein i=201 to 600, that are based on Formula 25

L_(Ai-26), wherein i=201 to 600, that are based on Formula 26

L_(Ai-27), wherein i=201 to 600, that are based on Formula 2i

L_(Ai-28), wherein i=201 to 600, that are based on Formula 28

L_(Ai-29), wherein i=201 to 600, that are based on Formula 29

wherein R, R^(D) and G are defined as follows: L_(Ai) R R^(D) G L_(A201)R¹ R¹ G¹ L_(A202) R¹ R¹ G² L_(A203) R¹ R¹ G³ L_(A204) R¹ R¹ G⁴ L_(A205)R¹ R¹ G⁵ L_(A206) R¹ R¹ G⁶ L_(A207) R¹ R¹ G⁷ L_(A208) R¹ R¹ G⁸ L_(A209)R¹ R¹ G⁹ L_(A210) R¹ R¹ G¹⁰ L_(A211) R² R¹ G¹ L_(A212) R² R¹ G² L_(A213)R² R¹ G³ L_(A214) R² R¹ G⁴ L_(A215) R² R¹ G⁵ L_(A216) R² R¹ G⁶ L_(A217)R² R¹ G⁷ L_(A218) R² R¹ G⁸ L_(A219) R² R¹ G⁹ L_(A220) R² R¹ G¹⁰ L_(A221)R³ R¹ G¹ L_(A222) R³ R¹ G² L_(A223) R³ R¹ G³ L_(A224) R³ R¹ G⁴ L_(A225)R³ R¹ G⁵ L_(A226) R³ R¹ G⁶ L_(A227) R³ R¹ G⁷ L_(A228) R³ R¹ G⁸ L_(A229)R³ R¹ G⁹ L_(A230) R³ R¹ G¹⁰ L_(A231) R⁴ R¹ G¹ L_(A232) R⁴ R¹ G² L_(A233)R⁴ R¹ G³ L_(A234) R⁴ R¹ G⁴ L_(A235) R⁴ R¹ G⁵ L_(A236) R⁴ R¹ G⁶ L_(A237)R⁴ R¹ G⁷ L_(A238) R⁴ R¹ G⁸ L_(A239) R⁴ R¹ G⁹ L_(A240) R⁴ R¹ G¹⁰ L_(A241)R⁵ R¹ G¹ L_(A242) R⁵ R¹ G² L_(A243) R⁵ R¹ G³ L_(A244) R⁵ R¹ G⁴ L_(A245)R⁵ R¹ G⁵ L_(A246) R⁵ R¹ G⁶ L_(A247) R⁵ R¹ G⁷ L_(A248) R⁵ R¹ G⁸ L_(A249)R⁵ R¹ G⁹ L_(A250) R⁵ R¹ G¹⁰ L_(A251) R⁶ R¹ G¹ L_(A252) R⁶ R¹ G² L_(A253)R⁶ R¹ G³ L_(A254) R⁶ R¹ G⁴ L_(A255) R⁶ R¹ G⁵ L_(A256) R⁶ R¹ G⁶ L_(A257)R⁶ R¹ G⁷ L_(A258) R⁶ R¹ G⁸ L_(A259) R⁶ R¹ G⁹ L_(A260) R⁶ R¹ G¹⁰ L_(A261)R⁷ R¹ G¹ L_(A262) R⁷ R¹ G² L_(A263) R⁷ R¹ G³ L_(A264) R⁷ R¹ G⁴ L_(A265)R⁷ R¹ G⁵ L_(A266) R⁷ R¹ G⁶ L_(A267) R⁷ R¹ G⁷ L_(A268) R⁷ R¹ G⁸ L_(A269)R⁷ R¹ G⁹ L_(A270) R⁷ R¹ G¹⁰ L_(A271) R⁸ R¹ G¹ L_(A272) R⁸ R¹ G² L_(A273)R⁸ R¹ G³ L_(A274) R⁸ R¹ G⁴ L_(A275) R⁸ R¹ G⁵ L_(A276) R⁸ R¹ G⁶ L_(A277)R⁸ R¹ G⁷ L_(A278) R⁸ R¹ G⁸ L_(A279) R⁸ R¹ G⁹ L_(A280) R⁸ R¹ G¹⁰ L_(A281)R⁹ R¹ G¹ L_(A282) R⁹ R¹ G² L_(A283) R⁹ R¹ G³ L_(A284) R⁹ R¹ G⁴ L_(A285)R⁹ R¹ G⁵ L_(A286) R⁹ R¹ G⁶ L_(A287) R⁹ R¹ G⁷ L_(A288) R⁹ R¹ G⁸ L_(A289)R⁹ R¹ G⁹ L_(A290) R⁹ R¹ G¹⁰ L_(A291) R¹⁰ R¹ G¹ L_(A292) R¹⁰ R¹ G²L_(A293) R¹⁰ R¹ G³ L_(A294) R¹⁰ R¹ G⁴ L_(A295) R¹⁰ R¹ G⁵ L_(A296) R¹⁰ R¹G⁶ L_(A297) R¹⁰ R¹ G⁷ L_(A298) R¹⁰ R¹ G⁸ L_(A299) R¹⁰ R¹ G⁹ L_(A300) R¹⁰R¹ G¹⁰ L_(A301) R¹¹ R¹ G¹ L_(A302) R¹¹ R¹ G² L_(A303) R¹¹ R¹ G³ L_(A304)R¹¹ R¹ G⁴ L_(A305) R¹¹ R¹ G⁵ L_(A306) R¹¹ R¹ G⁶ L_(A307) R¹¹ R¹ G⁷L_(A308) R¹¹ R¹ G⁸ L_(A309) R¹¹ R¹ G⁹ L_(A310) R¹¹ R¹ G¹⁰ L_(A311) R¹²R¹ G¹ L_(A312) R¹² R¹ G² L_(A313) R¹² R¹ G³ L_(A314) R¹² R¹ G⁴ L_(A315)R¹² R¹ G⁵ L_(A316) R¹² R¹ G⁶ L_(A317) R¹² R¹ G⁷ L_(A318) R¹² R¹ G⁸L_(A319) R¹² R¹ G⁹ L_(A320) R¹² R¹ G¹⁰ L_(A321) R¹³ R¹ G¹ L_(A322) R¹³R¹ G² L_(A323) R¹³ R¹ G³ L_(A324) R¹³ R¹ G⁴ L_(A325) R¹³ R¹ G⁵ L_(A326)R¹³ R¹ G⁶ L_(A327) R¹³ R¹ G⁷ L_(A328) R¹³ R¹ G⁸ L_(A329) R¹³ R¹ G⁹L_(A330) R¹³ R¹ G¹⁰ L_(A331) R¹⁴ R¹ G¹ L_(A332) R¹⁴ R¹ G² L_(A333) R¹⁴R¹ G³ L_(A334) R¹⁴ R¹ G⁴ L_(A335) R¹⁴ R¹ G⁵ L_(A336) R¹⁴ R¹ G⁶ L_(A337)R¹⁴ R¹ G⁷ L_(A338) R¹⁴ R¹ G⁸ L_(A339) R¹⁴ R¹ G⁹ L_(A340) R¹⁴ R¹ G¹⁰L_(A341) R¹⁵ R¹ G¹ L_(A342) R¹⁵ R¹ G² L_(A343) R¹⁵ R¹ G³ L_(A344) R¹⁵ R¹G⁴ L_(A345) R¹⁵ R¹ G⁵ L_(A346) R¹⁵ R¹ G⁶ L_(A347) R¹⁵ R¹ G⁷ L_(A348) R¹⁵R¹ G⁸ L_(A349) R¹⁵ R¹ G⁹ L_(A350) R¹⁵ R¹ G¹⁰ L_(A351) R¹⁶ R¹ G¹ L_(A352)R¹⁶ R¹ G² L_(A353) R¹⁶ R¹ G³ L_(A354) R¹⁶ R¹ G⁴ L_(A355) R¹⁶ R¹ G⁵L_(A356) R¹⁶ R¹ G⁶ L_(A357) R¹⁶ R¹ G⁷ L_(A358) R¹⁶ R¹ G⁸ L_(A359) R¹⁶ R¹G⁹ L_(A360) R¹⁶ R¹ G¹⁰ L_(A361) R¹⁷ R¹ G¹ L_(A362) R¹⁷ R¹ G² L_(A363)R¹⁷ R¹ G³ L_(A364) R¹⁷ R¹ G⁴ L_(A365) R¹⁷ R¹ G⁵ L_(A366) R¹⁷ R¹ G⁶L_(A367) R¹⁷ R¹ G⁷ L_(A368) R¹⁷ R¹ G⁸ L_(A369) R¹⁷ R¹ G⁹ L_(A370) R¹⁷ R¹G¹⁰ L_(A371) R¹⁸ R¹ G¹ L_(A372) R¹⁸ R¹ G² L_(A373) R¹⁸ R¹ G³ L_(A374)R¹⁸ R¹ G⁴ L_(A375) R¹⁸ R¹ G⁵ L_(A376) R¹⁸ R¹ G⁶ L_(A377) R¹⁸ R¹ G⁷L_(A378) R¹⁸ R¹ G⁸ L_(A379) R¹⁸ R¹ G⁹ L_(A380) R¹⁸ R¹ G¹⁰ L_(A381) R¹⁹R¹ G¹ L_(A382) R¹⁹ R¹ G² L_(A383) R¹⁹ R¹ G³ L_(A384) R¹⁹ R¹ G⁴ L_(A385)R¹⁹ R¹ G⁵ L_(A386) R¹⁹ R¹ G⁶ L_(A387) R¹⁹ R¹ G⁷ L_(A388) R¹⁹ R¹ G⁸L_(A389) R¹⁹ R¹ G⁹ L_(A390) R¹⁹ R¹ G¹⁰ L_(A391) R²⁰ R¹ G¹ L_(A392) R²⁰R¹ G² L_(A393) R²⁰ R¹ G³ L_(A394) R²⁰ R¹ G⁴ L_(A395) R²⁰ R¹ G⁵ L_(A396)R²⁰ R¹ G⁶ L_(A397) R²⁰ R¹ G⁷ L_(A398) R²⁰ R¹ G⁸ L_(A399) R²⁰ R¹ G⁹L_(A400) R²⁰ R¹ G¹⁰ L_(A401) R¹ R⁴ G¹ L_(A402) R¹ R⁴ G² L_(A403) R¹ R⁴G³ L_(A404) R¹ R⁴ G⁴ L_(A405) R¹ R⁴ G⁵ L_(A406) R¹ R⁴ G⁶ L_(A407) R¹ R⁴G⁷ L_(A408) R¹ R⁴ G⁸ L_(A409) R¹ R⁴ G⁹ L_(A410) R¹ R⁴ G¹⁰ L_(A411) R² R⁴G¹ L_(A412) R² R⁴ G² L_(A413) R² R⁴ G³ L_(A414) R² R⁴ G⁴ L_(A415) R² R⁴G⁵ L_(A416) R² R⁴ G⁶ L_(A417) R² R⁴ G⁷ L_(A418) R² R⁴ G⁸ L_(A419) R² R⁴G⁹ L_(A420) R² R⁴ G¹⁰ L_(A421) R³ R⁴ G¹ L_(A422) R³ R⁴ G² L_(A423) R³ R⁴G³ L_(A424) R³ R⁴ G⁴ L_(A425) R³ R⁴ G⁵ L_(A426) R³ R⁴ G⁶ L_(A427) R³ R⁴G⁷ L_(A428) R³ R⁴ G⁸ L_(A429) R³ R⁴ G⁹ L_(A430) R³ R⁴ G¹⁰ L_(A431) R⁴ R⁴G¹ L_(A432) R⁴ R⁴ G² L_(A433) R⁴ R⁴ G³ L_(A434) R⁴ R⁴ G⁴ L_(A435) R⁴ R⁴G⁵ L_(A436) R⁴ R⁴ G⁶ L_(A437) R⁴ R⁴ G⁷ L_(A438) R⁴ R⁴ G⁸ L_(A439) R⁴ R⁴G⁹ L_(A440) R⁴ R⁴ G¹⁰ L_(A441) R⁵ R⁴ G¹ L_(A442) R⁵ R⁴ G² L_(A443) R⁵ R⁴G³ L_(A444) R⁵ R⁴ G⁴ L_(A445) R⁵ R⁴ G⁵ L_(A446) R⁵ R⁴ G⁶ L_(A447) R⁵ R⁴G⁷ L_(A448) R⁵ R⁴ G⁸ L_(A449) R⁵ R⁴ G⁹ L_(A450) R⁵ R⁴ G¹⁰ L_(A451) R⁶ R⁴G¹ L_(A452) R⁶ R⁴ G² L_(A453) R⁶ R⁴ G³ L_(A454) R⁶ R⁴ G⁴ L_(A455) R⁶ R⁴G⁵ L_(A456) R⁶ R⁴ G⁶ L_(A457) R⁶ R⁴ G⁷ L_(A458) R⁶ R⁴ G⁸ L_(A459) R⁶ R⁴G⁹ L_(A460) R⁶ R⁴ G¹⁰ L_(A461) R⁷ R⁴ G¹ L_(A462) R⁷ R⁴ G² L_(A463) R⁷ R⁴G³ L_(A464) R⁷ R⁴ G⁴ L_(A465) R⁷ R⁴ G⁵ L_(A466) R⁷ R⁴ G⁶ L_(A467) R⁷ R⁴G⁸ L_(A468) R⁷ R⁴ G⁹ L_(A469) R⁷ R⁴ G¹⁰ L_(A470) R⁸ R⁴ G¹ L_(A471) R⁸ R⁴G² L_(A472) R⁸ R⁴ G³ L_(A473) R⁸ R⁴ G⁴ L_(A474) R⁸ R⁴ G⁵ L_(A475) R⁸ R⁴G⁶ L_(A476) R⁸ R⁴ G⁷ L_(A477) R⁸ R⁴ G⁸ L_(A478) R⁸ R⁴ G⁹ L_(A479) R⁸ R⁴G¹⁰ L_(A480) R⁹ R⁴ G¹ L_(A481) R⁹ R⁴ G² L_(A482) R⁹ R⁴ G³ L_(A483) R⁹ R⁴G⁴ L_(A484) R⁹ R⁴ G⁵ L_(A485) R⁹ R⁴ G⁶ L_(A486) R⁹ R⁴ G⁷ L_(A487) R⁹ R⁴G⁸ L_(A488) R⁹ R⁴ G⁹ L_(A489) R⁹ R⁴ G¹⁰ L_(A490) R¹⁰ R⁴ G¹ L_(A491) R¹⁰R⁴ G² L_(A492) R¹⁰ R⁴ G³ L_(A493) R¹⁰ R⁴ G⁴ L_(A494) R¹⁰ R⁴ G⁵ L_(A495)R¹⁰ R⁴ G⁶ L_(A496) R¹⁰ R⁴ G⁷ L_(A497) R¹⁰ R⁴ G⁸ L_(A498) R¹⁰ R⁴ G⁹L_(A499) R¹⁰ R⁴ G¹⁰ L_(A500) R¹¹ R⁴ G¹ L_(A501) R¹¹ R⁴ G² L_(A502) R¹¹R⁴ G³ L_(A503) R¹¹ R⁴ G⁴ L_(A504) R¹¹ R⁴ G⁵ L_(A505) R¹¹ R⁴ G⁶ L_(A506)R¹¹ R⁴ G⁷ L_(A507) R¹¹ R⁴ G⁸ L_(A508) R¹¹ R⁴ G⁹ L_(A509) R¹¹ R⁴ G¹⁰L_(A510) R¹² R⁴ G¹ L_(A511) R¹² R⁴ G² L_(A512) R¹² R⁴ G³ L_(A513) R¹² R⁴G⁴ L_(A514) R¹² R⁴ G⁵ L_(A515) R¹² R⁴ G⁶ L_(A516) R¹² R⁴ G⁷ L_(A517) R¹²R⁴ G⁸ L_(A518) R¹² R⁴ G⁹ L_(A519) R¹² R⁴ G¹⁰ L_(A520) R¹³ R⁴ G¹ L_(A521)R¹³ R⁴ G² L_(A522) R¹³ R⁴ G³ L_(A523) R¹³ R⁴ G⁴ L_(A524) R¹³ R⁴ G⁵L_(A525) R¹³ R⁴ G⁶ L_(A526) R¹³ R⁴ G⁷ L_(A527) R¹³ R⁴ G⁸ L_(A528) R¹³ R⁴G⁹ L_(A529) R¹³ R⁴ G¹⁰ L_(A530) R¹⁴ R⁴ G¹ L_(A531) R¹⁴ R⁴ G² L_(A532)R¹⁴ R⁴ G³ L_(A533) R¹⁴ R⁴ G⁴ L_(A534) R¹⁴ R⁴ G⁵ L_(A535) R¹⁴ R⁴ G⁶L_(A536) R¹⁴ R⁴ G⁷ L_(A537) R¹⁴ R⁴ G⁸ L_(A538) R¹⁴ R⁴ G⁹ L_(A539) R¹⁴ R⁴G¹⁰ L_(A540) R¹⁵ R⁴ G¹ L_(A541) R¹⁵ R⁴ G² L_(A542) R¹⁵ R⁴ G³ L_(A543)R¹⁵ R⁴ G⁴ L_(A544) R¹⁵ R⁴ G⁵ L_(A545) R¹⁵ R⁴ G⁶ L_(A546) R¹⁵ R⁴ G⁷L_(A547) R¹⁵ R⁴ G⁸ L_(A548) R¹⁵ R⁴ G⁹ L_(A549) R¹⁵ R⁴ G¹⁰ L_(A550) R¹⁶R⁴ G¹ L_(A551) R¹⁶ R⁴ G² L_(A552) R¹⁶ R⁴ G³ L_(A553) R¹⁶ R⁴ G⁴ L_(A554)R¹⁶ R⁴ G⁵ L_(A555) R¹⁶ R⁴ G⁶ L_(A556) R¹⁶ R⁴ G⁷ L_(A557) R¹⁶ R⁴ G⁸L_(A558) R¹⁶ R⁴ G⁹ L_(A559) R¹⁶ R⁴ G¹⁰ L_(A560) R¹⁷ R⁴ G¹ L_(A561) R¹⁷R⁴ G² L_(A562) R¹⁷ R⁴ G³ L_(A563) R¹⁷ R⁴ G⁴ L_(A564) R¹⁷ R⁴ G⁵ L_(A565)R¹⁷ R⁴ G⁶ L_(A566) R¹⁷ R⁴ G⁷ L_(A567) R¹⁷ R⁴ G⁸ L_(A568) R¹⁷ R⁴ G⁹L_(A569) R¹⁷ R⁴ G¹⁰ L_(A570) R¹⁸ R⁴ G¹ L_(A571) R¹⁸ R⁴ G² L_(A572) R¹⁸R⁴ G³ L_(A573) R¹⁸ R⁴ G⁴ L_(A574) R¹⁸ R⁴ G⁵ L_(A575) R¹⁸ R⁴ G⁶ L_(A576)R¹⁸ R⁴ G⁷ L_(A577) R¹⁸ R⁴ G⁸ L_(A578) R¹⁸ R⁴ G⁹ L_(A579) R¹⁸ R⁴ G¹⁰L_(A580) R¹⁹ R⁴ G¹ L_(A581) R¹⁹ R⁴ G² L_(A582) R¹⁹ R⁴ G³ L_(A583) R¹⁹ R⁴G⁴ L_(A584) R¹⁹ R⁴ G⁵ L_(A585) R¹⁹ R⁴ G⁶ L_(A586) R¹⁹ R⁴ G⁷ L_(A587) R¹⁹R⁴ G⁸ L_(A588) R¹⁹ R⁴ G⁹ L_(A589) R¹⁹ R⁴ G¹⁰ L_(A590) R²⁰ R⁴ G¹ L_(A591)R²⁰ R⁴ G² L_(A592) R²⁰ R⁴ G³ L_(A593) R²⁰ R⁴ G⁴ L_(A594) R²⁰ R⁴ G⁵L_(A595) R²⁰ R⁴ G⁶ L_(A596) R²⁰ R⁴ G⁷ L_(A597) R²⁰ R⁴ G⁸ L_(A598) R²⁰ R⁴G⁹ L_(A599) R²⁰ R⁴ G¹⁰ L_(A600) R²⁰ R⁴ G¹⁰

L_(Ai-30), wherein i=601 to 610, that are based on Formula 30

L_(Ai-31), wherein i=601 to 610, that are based on Formula 31

L_(Ai-32), wherein i=601 to 610, that are based on Formula 32

L_(Ai-33), wherein i=601 to 610, that are based on Formula 33

L_(Ai-34), wherein i=601 to 610, that are based on Formula 34

L_(Ai-35), wherein i=601 to 610, that are based on Formula 35

L_(Ai-36), wherein i=601 to 610, that are based on Formula 36

L_(Ai-37), wherein i=601 to 610, that are based on Formula 37

L_(Ai-38), wherein i=601 to 610, that are based on Formula 38

wherein G is defined as follows: Ligand G Ligand G Ligand G Ligand GLigand G Ligand G L_(A601) G¹ L_(A602) G² L_(A603) G³ L_(A604) G⁴L_(A605) G⁵ L_(A606) G⁶ L_(A607) G⁷ L_(A608) G⁸ L_(A609) G⁹ L_(A610) G¹⁰

wherein R¹ to R²⁰ have the following structures:

and wherein G¹ to G¹⁰ have the following structures:


15. The compound of claim 1, wherein the compound has a formula ofM(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) wherein L_(B) and L_(C) are each abidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0,1, or 2; and x+y+z is the oxidation state of the metal M. 16.-18.(canceled)
 19. The compound of claim 15, wherein L_(B) and L_(C) areeach independently selected from the group consisting of:

wherein, each Y¹ to Y¹³ is independently selected from the groupconsisting of carbon and nitrogen; Y′ is selected from the groupconsisting of B R_(e), N R_(e), P R_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) can befused or joined to form a ring; each R_(a), R_(b), R_(e), and R_(d) canindependently represent from mono to the maximum possible number ofsubstitutions, or no substitution; each R_(a), R_(b), R_(e), R_(d),R_(e) and R_(f) is independently a hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl,acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl,sulfinyl, sulfonyl, phosphino, boryl, and combinations thereof; and anytwo adjacent substituents of R_(a), R_(b), R_(c), and R_(d) can be fusedor joined to form a ring or form a multidentate ligand.
 20. (canceled)21. The compound of claim 16, wherein the compound is the CompoundA_(x-F) having the formula Ir(L_(Ai-f))₃, the Compound By-F having theformula Ir(L_(Ai-f))(L_(Bk))₂, or the Compound Cz-F having the formulaIr(L_(Ai-f))₂(L_(Cj)); wherein x=i, F=f, y=2631+k-263, and z=768i+j-768;wherein i is an integer from 1 to 610, and f is an integer from 1 to 38,and k is an integer from 1 to 263, and j is an integer from 1 to 768;wherein ligands L_(Bk) have the structures L_(B1) to L_(B263) defined asfollows:

wherein ligands L_(Cj) have the structure of L_(Cj-I), having thestructures based on a structure of

or L_(Cj-II), having the structures based on a structure of

wherein for each L_(Cj) in L_(Cj-I) and L_(Cj-II), R¹ and R² are definedas provided below: L_(Cj) R¹ R² L_(C1) R^(D1) R^(D1) L_(C2) R^(D2)R^(D2) L_(C3) R^(D3) R^(D3) L_(C4) R^(D4) R^(D4) L_(C5) R^(D5) R^(D5)L_(C6) R^(D6) R^(D6) L_(C7) R^(D7) R^(D7) L_(C8) R^(D8) R^(D8) L_(C9)R^(D9) R^(D9) L_(C10) R^(D10) R^(D10) L_(C11) R^(D11) R^(D11) L_(C12)R^(D12) R^(D12) L_(C13) R^(D13) R^(D13) L_(C14) R^(D14) R^(D14) L_(C15)R^(D15) R^(D15) L_(C16) R^(D16) R^(D16) L_(C17) R^(D17) R^(D17) L_(C18)R^(D18) R^(D18) L_(C19) R^(D19) R^(D19) L_(C20) R^(D20) R^(D20) L_(C21)R^(D21) R^(D21) L_(C22) R^(D22) R^(D22) L_(C23) R^(D23) R^(D23) L_(C24)R^(D24) R^(D24) L_(C25) R^(D25) R^(D25) L_(C26) R^(D26) R^(D26) L_(C27)R^(D27) R^(D27) L_(C28) R^(D28) R^(D28) L_(C29) R^(D29) R^(D29) L_(C30)R^(D30) R^(D30) L_(C31) R^(D31) R^(D31) L_(C32) R^(D32) R^(D32) L_(C33)R^(D33) R^(D33) L_(C34) R^(D34) R^(D34) L_(C35) R^(D35) R^(D35) L_(C36)R^(D36) R^(D36) L_(C37) R^(D37) R^(D37) L_(C38) R^(D38) R^(D38) L_(C39)R^(D39) R^(D39) L_(C40) R^(D40) R^(D40) L_(C41) R^(D41) R^(D41) L_(C42)R^(D42) R^(D42) L_(C43) R^(D43) R^(D43) L_(C44) R^(D44) R^(D44) L_(C45)R^(D45) R^(D45) L_(C46) R^(D46) R^(D46) L_(C47) R^(D47) R^(D47) L_(C48)R^(D48) R^(D48) L_(C49) R^(D49) R^(D49) L_(C50) R^(D50) R^(D50) L_(C51)R^(D51) R^(D51) L_(C52) R^(D52) R^(D52) L_(C53) R^(D53) R^(D53) L_(C54)R^(D54) R^(D54) L_(C55) R^(D55) R^(D55) L_(C56) R^(D56) R^(D56) L_(C57)R^(D57) R^(D57) L_(C58) R^(D58) R^(D58) L_(C59) R^(D59) R^(D59) L_(C60)R^(D60) R^(D60) L_(C61) R^(D61) R^(D61) L_(C62) R^(D62) R^(D62) L_(C63)R^(D63) R^(D63) L_(C64) R^(D64) R^(D64) L_(C65) R^(D65) R^(D65) L_(C66)R^(D66) R^(D66) L_(C67) R^(D67) R^(D67) L_(C68) R^(D68) R^(D68) L_(C69)R^(D69) R^(D69) L_(C70) R^(D70) R^(D70) L_(C71) R^(D71) R^(D71) L_(C72)R^(D72) R^(D72) L_(C73) R^(D73) R^(D73) L_(C74) R^(D74) R^(D74) L_(C75)R^(D75) R^(D75) L_(C76) R^(D76) R^(D76) L_(C77) R^(D77) R^(D77) L_(C78)R^(D78) R^(D78) L_(C79) R^(D79) R^(D79) L_(C80) R^(D80) R^(D80) L_(C81)R^(D81) R^(D81) L_(C82) R^(D82) R^(D82) L_(C83) R^(D83) R^(D83) L_(C84)R^(D84) R^(D84) L_(C85) R^(D85) R^(D85) L_(C86) R^(D86) R^(D86) L_(C87)R^(D87) R^(D87) L_(C88) R^(D88) R^(D88) L_(C89) R^(D89) R^(D89) L_(C90)R^(D90) R^(D90) L_(C91) R^(D91) R^(D91) L_(C92) R^(D92) R^(D92) L_(C93)R^(D93) R^(D93) L_(C94) R^(D94) R^(D94) L_(C95) R^(D95) R^(D95) L_(C96)R^(D96) R^(D96) L_(C97) R^(D97) R^(D97) L_(C98) R^(D98) R^(D98) L_(C99)R^(D99) R^(D99) L_(C100) R^(D100) R^(D100) L_(C101) R^(D101) R^(D101)L_(C102) R^(D102) R^(D102) L_(C103) R^(D103) R^(D103) L_(C104) R^(D104)R^(D104) L_(C105) R^(D105) R^(D105) L_(C106) R^(D106) R^(D106) L_(C107)R^(D107) R^(D107) L_(C108) R^(D108) R^(D108) L_(C109) R^(D109) R^(D109)L_(C110) R^(D110) R^(D110) L_(C111) R^(D111) R^(D111) L_(C112) R^(D112)R^(D112) L_(C113) R^(D113) R^(D113) L_(C114) R^(D114) R^(D114) L_(C115)R^(D115) R^(D115) L_(C116) R^(D116) R^(D116) L_(C117) R^(D117) R^(D117)L_(C118) R^(D118) R^(D118) L_(C119) R^(D119) R^(D119) L_(C120) R^(D120)R^(D120) L_(C121) R^(D121) R^(D121) L_(C122) R^(D122) R^(D122) L_(C123)R^(D123) R^(D123) L_(C124) R^(D124) R^(D124) L_(C125) R^(D125) R^(D125)L_(C126) R^(D126) R^(D126) L_(C127) R^(D127) R^(D127) L_(C128) R^(D128)R^(D128) L_(C129) R^(D129) R^(D129) L_(C130) R^(D130) R^(D130) L_(C131)R^(D131) R^(D131) L_(C132) R^(D132) R^(D132) L_(C133) R^(D133) R^(D133)L_(C134) R^(D134) R^(D134) L_(C135) R^(D135) R^(D135) L_(C136) R^(D136)R^(D136) L_(C137) R^(D137) R^(D137) L_(C138) R^(D138) R^(D138) L_(C139)R^(D139) R^(D139) L_(C140) R^(D140) R^(D140) L_(C141) R^(D141) R^(D141)L_(C142) R^(D142) R^(D142) L_(C143) R^(D143) R^(D143) L_(C144) R^(D144)R^(D144) L_(C145) R^(D145) R^(D145) L_(C146) R^(D146) R^(D146) L_(C147)R^(D147) R^(D147) L_(C148) R^(D148) R^(D148) L_(C149) R^(D149) R^(D149)L_(C150) R^(D150) R^(D150) L_(C151) R^(D151) R^(D151) L_(C152) R^(D152)R^(D152) L_(C153) R^(D153) R^(D153) L_(C154) R^(D154) R^(D154) L_(C155)R^(D155) R^(D155) L_(C156) R^(D156) R^(D156) L_(C157) R^(D157) R^(D157)L_(C158) R^(D158) R^(D158) L_(C159) R^(D159) R^(D159) L_(C160) R^(D160)R^(D160) L_(C161) R^(D161) R^(D161) L_(C162) R^(D162) R^(D162) L_(C163)R^(D163) R^(D163) L_(C164) R^(D164) R^(D164) L_(C165) R^(D165) R^(D165)L_(C166) R^(D166) R^(D166) L_(C167) R^(D167) R^(D167) L_(C168) R^(D168)R^(D168) L_(C169) R^(D169) R^(D169) L_(C170) R^(D170) R^(D170) L_(C171)R^(D171) R^(D171) L_(C172) R^(D172) R^(D172) L_(C173) R^(D173) R^(D173)L_(C174) R^(D174) R^(D174) L_(C175) R^(D175) R^(D175) L_(C176) R^(D176)R^(D176) L_(C177) R^(D177) R^(D177) L_(C178) R^(D178) R^(D178) L_(C179)R^(D179) R^(D179) L_(C180) R^(D180) R^(D180) L_(C181) R^(D181) R^(D181)L_(C182) R^(D182) R^(D182) L_(C183) R^(D183) R^(D183) L_(C184) R^(D184)R^(D184) L_(C185) R^(D185) R^(D185) L_(C186) R^(D186) R^(D186) L_(C187)R^(D187) R^(D187) L_(C188) R^(D188) R^(D188) L_(C189) R^(D189) R^(D189)L_(C190) R^(D190) R^(D190) L_(C191) R^(D191) R^(D191) L_(C192) R^(D192)R^(D192) L_(C193) R^(D1) R^(D3) L_(C194) R^(D1) R^(D4) L_(C195) R^(D1)R^(D5) L_(C196) R^(D1) R^(D9) L_(C197) R^(D1) R^(D10) L_(C198) R^(D1)R^(D17) L_(C199) R^(D1) R^(D18) L_(C200) R^(D1) R^(D20) L_(C201) R^(D1)R^(D22) L_(C202) R^(D1) R^(D37) L_(C203) R^(D1) R^(D40) L_(C204) R^(D1)R^(D41) L_(C205) R^(D1) R^(D42) L_(C206) R^(D1) R^(D43) L_(C207) R^(D1)R^(D48) L_(C208) R^(D1) R^(D49) L_(C209) R^(D1) R^(D50) L_(C210) R^(D1)R^(D54) L_(C211) R^(D1) R^(D55) L_(C212) R^(D1) R^(D58) L_(C213) R^(D1)R^(D59) L_(C214) R^(D1) R^(D78) L_(C215) R^(D1) R^(D79) L_(C216) R^(D1)R^(D81) L_(C217) R^(D1) R^(D87) L_(C218) R^(D1) R^(D88) L_(C219) R^(D1)R^(D89) L_(C220) R^(D1) R^(D93) L_(C221) R^(D1) R^(D116) L_(C222) R^(D1)R^(D117) L_(C223) R^(D1) R^(D118) L_(C224) R^(D1) R^(D119) L_(C225)R^(D1) R^(D120) L_(C226) R^(D1) R^(D133) L_(C227) R^(D1) R^(D134)L_(C228) R^(D1) R^(D135) L_(C229) R^(D1) R^(D136) L_(C230) R^(D1)R^(D143) L_(C231) R^(D1) R^(D144) L_(C232) R^(D1) R^(D145) L_(C233)R^(D1) R^(D146) L_(C234) R^(D1) R^(D147) L_(C235) R^(D1) R^(D149)L_(C236) R^(D1) R^(D151) L_(C237) R^(D1) R^(D154) L_(C238) R^(D1)R^(D155) L_(C239) R^(D1) R^(D161) L_(C240) R^(D1) R^(D175) L_(C241)R^(D4) R^(D3) L_(C242) R^(D4) R^(D5) L_(C243) R^(D4) R^(D9) L_(C244)R^(D4) R^(D10) L_(C245) R^(D4) R^(D17) L_(C246) R^(D4) R^(D18) L_(C247)R^(D4) R^(D20) L_(C248) R^(D4) R^(D22) L_(C249) R^(D4) R^(D37) L_(C250)R^(D4) R^(D40) L_(C251) R^(D4) R^(D41) L_(C252) R^(D4) R^(D42) L_(C253)R^(D4) R^(D43) L_(C254) R^(D4) R^(D48) L_(C255) R^(D4) R^(D49) L_(C256)R^(D4) R^(D50) L_(C257) R^(D4) R^(D54) L_(C258) R^(D4) R^(D55) L_(C259)R^(D4) R^(D58) L_(C260) R^(D4) R^(D59) L_(C261) R^(D4) R^(D78) L_(C262)R^(D4) R^(D79) L_(C263) R^(D4) R^(D81) L_(C264) R^(D4) R^(D87) L_(C265)R^(D4) R^(D88) L_(C266) R^(D4) R^(D89) L_(C267) R^(D4) R^(D93) L_(C268)R^(D4) R^(D116) L_(C269) R^(D4) R^(D117) L_(C270) R^(D4) R^(D118)L_(C271) R^(D4) R^(D119) L_(C272) R^(D4) R^(D120) L_(C273) R^(D4)R^(D133) L_(C274) R^(D4) R^(D134) L_(C275) R^(D4) R^(D135) L_(C276)R^(D4) R^(D136) L_(C277) R^(D4) R^(D143) L_(C278) R^(D4) R^(D144)L_(C279) R^(D4) R^(D145) L_(C280) R^(D4) R^(D146) L_(C281) R^(D4)R^(D147) L_(C282) R^(D4) R^(D149) L_(C283) R^(D4) R^(D151) L_(C284)R^(D4) R^(D154) L_(C285) R^(D4) R^(D155) L_(C286) R^(D4) R^(D161)L_(C287) R^(D4) R^(D175) L_(C288) R^(D9) R^(D3) L_(C289) R^(D9) R^(D5)L_(C290) R^(D9) R^(D10) L_(C291) R^(D9) R^(D17) L_(C292) R^(D9) R^(D18)L_(C293) R^(D9) R^(D20) L_(C294) R^(D9) R^(D22) L_(C295) R^(D9) R^(D37)L_(C296) R^(D9) R^(D40) L_(C297) R^(D9) R^(D41) L_(C298) R^(D9) R^(D42)L_(C299) R^(D9) R^(D43) L_(C300) R^(D9) R^(D48) L_(C301) R^(D9) R^(D49)L_(C302) R^(D9) R^(D50) L_(C303) R^(D9) R^(D54) L_(C304) R^(D9) R^(D55)L_(C305) R^(D9) R^(D58) L_(C306) R^(D9) R^(D59) L_(C307) R^(D9) R^(D78)L_(C308) R^(D9) R^(D79) L_(C309) R^(D9) R^(D81) L_(C310) R^(D9) R^(D87)L_(C311) R^(D9) R^(D88) L_(C312) R^(D9) R^(D89) L_(C313) R^(D9) R^(D93)L_(C314) R^(D9) R^(D116) L_(C315) R^(D9) R^(D117) L_(C316) R^(D9)R^(D118) L_(C317) R^(D9) R^(D119) L_(C318) R^(D9) R^(D120) L_(C319)R^(D9) R^(D133) L_(C320) R^(D9) R^(D134) L_(C321) R^(D9) R^(D135)L_(C322) R^(D9) R^(D136) L_(C323) R^(D9) R^(D143) L_(C324) R^(D9)R^(D144) L_(C325) R^(D9) R^(D145) L_(C326) R^(D9) R^(D146) L_(C327)R^(D9) R^(D147) L_(C328) R^(D9) R^(D149) L_(C329) R^(D9) R^(D151)L_(C330) R^(D9) R^(D154) L_(C331) R^(D9) R^(D155) L_(C332) R^(D9)R^(D161) L_(C333) R^(D9) R^(D175) L_(C334) R^(D10) R^(D3) L_(C335)R^(D10) R^(D5) L_(C336) R^(D10) R^(D17) L_(C337) R^(D10) R^(D18)L_(C338) R^(D10) R^(D20) L_(C339) R^(D10) R^(D22) L_(C340) R^(D10)R^(D37) L_(C341) R^(D10) R^(D40) L_(C342) R^(D10) R^(D41) L_(C343)R^(D10) R^(D42) L_(C344) R^(D10) R^(D43) L_(C345) R^(D10) R^(D48)L_(C346) R^(D10) R^(D49) L_(C347) R^(D10) R^(D50) L_(C348) R^(D10)R^(D54) L_(C349) R^(D10) R^(D55) L_(C350) R^(D10) R^(D58) L_(C351)R^(D10) R^(D59) L_(C352) R^(D10) R^(D78) L_(C353) R^(D10) R^(D79)L_(C354) R^(D10) R^(D81) L_(C355) R^(D10) R^(D87) L_(C356) R^(D10)R^(D88) L_(C357) R^(D10) R^(D89) L_(C358) R^(D10) R^(D93) L_(C359)R^(D10) R^(D116) L_(C360) R^(D10) R^(D117) L_(C361) R^(D10) R^(D118)L_(C362) R^(D10) R^(D119) L_(C363) R^(D10) R^(D120) L_(C364) R^(D10)R^(D133) L_(C365) R^(D10) R^(D134) L_(C366) R^(D10) R^(D135) L_(C367)R^(D10) R^(D136) L_(C368) R^(D10) R^(D143) L_(C369) R^(D10) R^(D144)L_(C370) R^(D10) R^(D145) L_(C371) R^(D10) R^(D146) L_(C372) R^(D10)R^(D147) L_(C373) R^(D10) R^(D149) L_(C374) R^(D10) R^(D151) L_(C375)R^(D10) R^(D154) L_(C376) R^(D10) R^(D155) L_(C377) R^(D10) R^(D161)L_(C378) R^(D10) R^(D175) L_(C379) R^(D17) R^(D3) L_(C380) R^(D17)R^(D5) L_(C381) R^(D17) R^(D18) L_(C382) R^(D17) R^(D20) L_(C383)R^(D17) R^(D22) L_(C384) R^(D17) R^(D37) L_(C385) R^(D17) R^(D40)L_(C386) R^(D17) R^(D41) L_(C387) R^(D17) R^(D42) L_(C388) R^(D17)R^(D43) L_(C389) R^(D17) R^(D48) L_(C390) R^(D17) R^(D49) L_(C391)R^(D17) R^(D50) L_(C392) R^(D17) R^(D54) L_(C393) R^(D17) R^(D55)L_(C394) R^(D17) R^(D58) L_(C395) R^(D17) R^(D59) L_(C396) R^(D17)R^(D78) L_(C397) R^(D17) R^(D79) L_(C398) R^(D17) R^(D81) L_(C399)R^(D17) R^(D87) L_(C400) R^(D17) R^(D88) L_(C401) R^(D17) R^(D89)L_(C402) R^(D17) R^(D93) L_(C403) R^(D17) R^(D116) L_(C404) R^(D17)R^(D117) L_(C405) R^(D17) R^(D118) L_(C406) R^(D17) R^(D119) L_(C407)R^(D17) R^(D120) L_(C408) R^(D17) R^(D133) L_(C409) R^(D17) R^(D134)L_(C410) R^(D17) R^(D135) L_(C411) R^(D17) R^(D136) L_(C412) R^(D17)R^(D143) L_(C413) R^(D17) R^(D144) L_(C414) R^(D17) R^(D145) L_(C415)R^(D17) R^(D146) L_(C416) R^(D17) R^(D147) L_(C417) R^(D17) R^(D149)L_(C418) R^(D17) R^(D151) L_(C419) R^(D17) R^(D154) L_(C420) R^(D17)R^(D155) L_(C421) R^(D17) R^(D161) L_(C422) R^(D17) R^(D175) L_(C423)R^(D50) R^(D3) L_(C424) R^(D50) R^(D5) L_(C425) R^(D50) R^(D18) L_(C426)R^(D50) R^(D20) L_(C427) R^(D50) R^(D22) L_(C428) R^(D50) R^(D37)L_(C429) R^(D50) R^(D40) L_(C430) R^(D50) R^(D41) L_(C431) R^(D50)R^(D42) L_(C432) R^(D50) R^(D43) L_(C433) R^(D50) R^(D48) L_(C434)R^(D50) R^(D49) L_(C435) R^(D50) R^(D54) L_(C436) R^(D50) R^(D55)L_(C437) R^(D50) R^(D58) L_(C438) R^(D50) R^(D59) L_(C439) R^(D50)R^(D78) L_(C440) R^(D50) R^(D79) L_(C441) R^(D50) R^(D81) L_(C442)R^(D50) R^(D87) L_(C443) R^(D50) R^(D88) L_(C444) R^(D50) R^(D89)L_(C445) R^(D50) R^(D93) L_(C446) R^(D50) R^(D116) L_(C447) R^(D50)R^(D117) L_(C448) R^(D50) R^(D118) L_(C449) R^(D50) R^(D119) L_(C450)R^(D50) R^(D120) L_(C451) R^(D50) R^(D133) L_(C452) R^(D50) R^(D134)L_(C453) R^(D50) R^(D135) L_(C454) R^(D50) R^(D136) L_(C455) R^(D50)R^(D143) L_(C456) R^(D50) R^(D144) L_(C457) R^(D50) R^(D145) L_(C458)R^(D50) R^(D146) L_(C459) R^(D50) R^(D147) L_(C460) R^(D50) R^(D149)L_(C461) R^(D50) R^(D151) L_(C462) R^(D50) R^(D154) L_(C463) R^(D50)R^(D155) L_(C464) R^(D50) R^(D161) L_(C465) R^(D50) R^(D175) L_(C466)R^(D55) R^(D3) L_(C467) R^(D55) R^(D5) L_(C468) R^(D55) R^(D18) L_(C469)R^(D55) R^(D20) L_(C470) R^(D55) R^(D22) L_(C471) R^(D55) R^(D37)L_(C472) R^(D55) R^(D40) L_(C473) R^(D55) R^(D41) L_(C474) R^(D55)R^(D42) L_(C475) R^(D55) R^(D43) L_(C476) R^(D55) R^(D48) L_(C477)R^(D55) R^(D49) L_(C478) R^(D55) R^(D54) L_(C479) R^(D55) R^(D58)L_(C480) R^(D55) R^(D59) L_(C481) R^(D55) R^(D78) L_(C482) R^(D55)R^(D79) L_(C483) R^(D55) R^(D81) L_(C484) R^(D55) R^(D87) L_(C485)R^(D55) R^(D88) L_(C486) R^(D55) R^(D89) L_(C487) R^(D55) R^(D93)L_(C488) R^(D55) R^(D116) L_(C489) R^(D55) R^(D117) L_(C490) R^(D55)R^(D118) L_(C491) R^(D55) R^(D119) L_(C492) R^(D55) R^(D120) L_(C493)R^(D55) R^(D133) L_(C494) R^(D55) R^(D134) L_(C495) R^(D55) R^(D135)L_(C496) R^(D55) R^(D136) L_(C497) R^(D55) R^(D143) L_(C498) R^(D55)R^(D144) L_(C499) R^(D55) R^(D145) L_(C500) R^(D55) R^(D146) L_(C501)R^(D55) R^(D147) L_(C502) R^(D55) R^(D149) L_(C503) R^(D55) R^(D151)L_(C504) R^(D55) R^(D154) L_(C505) R^(D55) R^(D155) L_(C506) R^(D55)R^(D161) L_(C507) R^(D55) R^(D175) L_(C508) R^(D116) R^(D3) L_(C509)R^(D116) R^(D5) L_(C510) R^(D116) R^(D17) L_(C511) R^(D116) R^(D18)L_(C512) R^(D116) R^(D20) L_(C513) R^(D116) R^(D22) L_(C514) R^(D116)R^(D37) L_(C515) R^(D116) R^(D40) L_(C516) R^(D116) R^(D41) L_(C517)R^(D116) R^(D42) L_(C518) R^(D116) R^(D43) L_(C519) R^(D116) R^(D48)L_(C520) R^(D116) R^(D49) L_(C521) R^(D116) R^(D54) L_(C522) R^(D116)R^(D58) L_(C523) R^(D116) R^(D59) L_(C524) R^(D116) R^(D78) L_(C525)R^(D116) R^(D79) L_(C526) R^(D116) R^(D81) L_(C527) R^(D116) R^(D87)L_(C528) R^(D116) R^(D88) L_(C529) R^(D116) R^(D89) L_(C530) R^(D116)R^(D93) L_(C531) R^(D116) R^(D117) L_(C532) R^(D116) R^(D118) L_(C533)R^(D116) R^(D119) L_(C534) R^(D116) R^(D120) L_(C535) R^(D116) R^(D133)L_(C536) R^(D116) R^(D134) L_(C537) R^(D116) R^(D135) L_(C538) R^(D116)R^(D136) L_(C539) R^(D116) R^(D143) L_(C540) R^(D116) R^(D144) L_(C541)R^(D116) R^(D145) L_(C542) R^(D116) R^(D146) L_(C543) R^(D116) R^(D147)L_(C544) R^(D116) R^(D149) L_(C545) R^(D116) R^(D151) L_(C546) R^(D116)R^(D154) L_(C547) R^(D116) R^(D155) L_(C548) R^(D116) R^(D161) L_(C549)R^(D116) R^(D175) L_(C550) R^(D143) R^(D3) L_(C551) R^(D143) R^(D5)L_(C552) R^(D143) R^(D17) L_(C553) R^(D143) R^(D18) L_(C554) R^(D143)R^(D20) L_(C555) R^(D143) R^(D22) L_(C556) R^(D143) R^(D37) L_(C557)R^(D143) R^(D40) L_(C558) R^(D143) R^(D41) L_(C559) R^(D143) R^(D42)L_(C560) R^(D143) R^(D43) L_(C561) R^(D143) R^(D48) L_(C562) R^(D143)R^(D49) L_(C563) R^(D143) R^(D54) L_(C564) R^(D143) R^(D58) L_(C565)R^(D143) R^(D59) L_(C566) R^(D143) R^(D78) L_(C567) R^(D143) R^(D79)L_(C568) R^(D143) R^(D81) L_(C569) R^(D143) R^(D87) L_(C570) R^(D143)R^(D88) L_(C571) R^(D143) R^(D89) L_(C572) R^(D143) R^(D93) L_(C573)R^(D143) R^(D116) L_(C574) R^(D143) R^(D117) L_(C575) R^(D143) R^(D118)L_(C576) R^(D143) R^(D119) L_(C577) R^(D143) R^(D120) L_(C578) R^(D143)R^(D133) L_(C579) R^(D143) R^(D134) L_(C580) R^(D143) R^(D135) L_(C581)R^(D143) R^(D136) L_(C582) R^(D143) R^(D144) L_(C583) R^(D143) R^(D145)L_(C584) R^(D143) R^(D146) L_(C585) R^(D143) R^(D147) L_(C586) R^(D143)R^(D149) L_(C587) R^(D143) R^(D151) L_(C588) R^(D143) R^(D154) L_(C589)R^(D143) R^(D155) L_(C590) R^(D143) R^(D161) L_(C591) R^(D143) R^(D175)L_(C592) R^(D144) R^(D3) L_(C593) R^(D144) R^(D5) L_(C594) R^(D144)R^(D17) L_(C595) R^(D144) R^(D18) L_(C596) R^(D144) R^(D20) L_(C597)R^(D144) R^(D22) L_(C598) R^(D144) R^(D37) L_(C599) R^(D144) R^(D40)L_(C600) R^(D144) R^(D41) L_(C601) R^(D144) R^(D42) L_(C602) R^(D144)R^(D43) L_(C603) R^(D144) R^(D48) L_(C604) R^(D144) R^(D49) L_(C605)R^(D144) R^(D54) L_(C606) R^(D144) R^(D58) L_(C607) R^(D144) R^(D59)L_(C608) R^(D144) R^(D78) L_(C609) R^(D144) R^(D79) L_(C610) R^(D144)R^(D81) L_(C611) R^(D144) R^(D87) L_(C612) R^(D144) R^(D88) L_(C613)R^(D144) R^(D89) L_(C614) R^(D144) R^(D93) L_(C615) R^(D144) R^(D116)L_(C616) R^(D144) R^(D117) L_(C617) R^(D144) R^(D118) L_(C618) R^(D144)R^(D119) L_(C619) R^(D144) R^(D120) L_(C620) R^(D144) R^(D133) L_(C621)R^(D144) R^(D134) L_(C622) R^(D144) R^(D135) L_(C623) R^(D144) R^(D136)L_(C624) R^(D144) R^(D145) L_(C625) R^(D144) R^(D146) L_(C626) R^(D144)R^(D147) L_(C627) R^(D144) R^(D149) L_(C628) R^(D144) R^(D151) L_(C629)R^(D144) R^(D154) L_(C630) R^(D144) R^(D155) L_(C631) R^(D144) R^(D161)L_(C632) R^(D144) R^(D175) L_(C633) R^(D145) R^(D3) L_(C634) R^(D145)R^(D5) L_(C635) R^(D145) R^(D17) L_(C636) R^(D145) R^(D18) L_(C637)R^(D145) R^(D20) L_(C638) R^(D145) R^(D22) L_(C639) R^(D145) R^(D37)L_(C640) R^(D145) R^(D40) L_(C641) R^(D145) R^(D41) L_(C642) R^(D145)R^(D42) L_(C643) R^(D145) R^(D43) L_(C644) R^(D145) R^(D48) L_(C645)R^(D145) R^(D49) L_(C646) R^(D145) R^(D54) L_(C647) R^(D145) R^(D58)L_(C648) R^(D145) R^(D59) L_(C649) R^(D145) R^(D78) L_(C650) R^(D145)R^(D79) L_(C651) R^(D145) R^(D81) L_(C652) R^(D145) R^(D87) L_(C653)R^(D145) R^(D88) L_(C654) R^(D145) R^(D89) L_(C655) R^(D145) R^(D93)L_(C656) R^(D145) R^(D116) L_(C657) R^(D145) R^(D117) L_(C658) R^(D145)R^(D118) L_(C659) R^(D145) R^(D119) L_(C660) R^(D145) R^(D120) L_(C661)R^(D145) R^(D133) L_(C662) R^(D145) R^(D134) L_(C663) R^(D145) R^(D135)L_(C664) R^(D145) R^(D136) L_(C665) R^(D145) R^(D146) L_(C666) R^(D145)R^(D147) L_(C667) R^(D145) R^(D149) L_(C668) R^(D145) R^(D151) L_(C669)R^(D145) R^(D154) L_(C670) R^(D145) R^(D155) L_(C671) R^(D145) R^(D161)L_(C672) R^(D145) R^(D175) L_(C673) R^(D146) R^(D3) L_(C674) R^(D146)R^(D5) L_(C675) R^(D146) R^(D17) L_(C676) R^(D146) R^(D18) L_(C677)R^(D146) R^(D20) L_(C678) R^(D146) R^(D22) L_(C679) R^(D146) R^(D37)L_(C680) R^(D146) R^(D40) L_(C681) R^(D146) R^(D41) L_(C682) R^(D146)R^(D42) L_(C683) R^(D146) R^(D43) L_(C684) R^(D146) R^(D48) L_(C685)R^(D146) R^(D49) L_(C686) R^(D146) R^(D54) L_(C687) R^(D146) R^(D58)L_(C688) R^(D146) R^(D59) L_(C689) R^(D146) R^(D78) L_(C690) R^(D146)R^(D79) L_(C691) R^(D146) R^(D81) L_(C692) R^(D146) R^(D87) L_(C693)R^(D146) R^(D88) L_(C694) R^(D146) R^(D89) L_(C695) R^(D146) R^(D93)L_(C696) R^(D146) R^(D117) L_(C697) R^(D146) R^(D118) L_(C698) R^(D146)R^(D119) L_(C699) R^(D146) R^(D120) L_(C700) R^(D146) R^(D133) L_(C701)R^(D146) R^(D134) L_(C702) R^(D146) R^(D135) L_(C703) R^(D146) R^(D136)L_(C704) R^(D146) R^(D146) L_(C705) R^(D146) R^(D147) L_(C706) R^(D146)R^(D149) L_(C707) R^(D146) R^(D151) L_(C708) R^(D146) R^(D154) L_(C709)R^(D146) R^(D155) L_(C710) R^(D146) R^(D161) L_(C711) R^(D146) R^(D175)L_(C712) R^(D133) R^(D3) L_(C713) R^(D133) R^(D5) L_(C714) R^(D133)R^(D3) L_(C715) R^(D133) R^(D18) L_(C716) R^(D133) R^(D20) L_(C717)R^(D133) R^(D22) L_(C718) R^(D133) R^(D37) L_(C719) R^(D133) R^(D40)L_(C720) R^(D133) R^(D41) L_(C721) R^(D133) R^(D42) L_(C722) R^(D133)R^(D43) L_(C723) R^(D133) R^(D48) L_(C724) R^(D133) R^(D49) L_(C725)R^(D133) R^(D54) L_(C726) R^(D133) R^(D58) L_(C727) R^(D133) R^(D59)L_(C728) R^(D133) R^(D78) L_(C729) R^(D133) R^(D79) L_(C730) R^(D133)R^(D81) L_(C731) R^(D133) R^(D87) L_(C732) R^(D133) R^(D88) L_(C733)R^(D133) R^(D89) L_(C734) R^(D133) R^(D93) L_(C735) R^(D133) R^(D117)L_(C736) R^(D133) R^(D118) L_(C737) R^(D133) R^(D119) L_(C738) R^(D133)R^(D120) L_(C739) R^(D133) R^(D133) L_(C740) R^(D133) R^(D134) L_(C741)R^(D133) R^(D135) L_(C742) R^(D133) R^(D136) L_(C743) R^(D133) R^(D146)L_(C744) R^(D133) R^(D147) L_(C745) R^(D133) R^(D149) L_(C746) R^(D133)R^(D151) L_(C747) R^(D133) R^(D154) L_(C748) R^(D133) R^(D155) L_(C749)R^(D133) R^(D161) L_(C750) R^(D133) R^(D175) L_(C751) R^(D175) R^(D3)L_(C752) R^(D175) R^(D5) L_(C753) R^(D175) R^(D18) L_(C754) R^(D175)R^(D20) L_(C755) R^(D175) R^(D22) L_(C756) R^(D175) R^(D37) L_(C757)R^(D175) R^(D40) L_(C758) R^(D175) R^(D41) L_(C759) R^(D175) R^(D42)L_(C760) R^(D175) R^(D43) L_(C761) R^(D175) R^(D48) L_(C762) R^(D175)R^(D49) L_(C763) R^(D175) R^(D54) L_(C764) R^(D175) R^(D58) L_(C765)R^(D175) R^(D59) L_(C766) R^(D175) R^(D78) L_(C767) R^(D175) R^(D79)L_(C768) R^(D175) R^(D81)

wherein R^(D1) to R^(D192) have the following structures:


22. The compound of claim 1, wherein the compound has a structure ofFormula II

wherein, rings C and D are each independently a 5-membered or 6-memberedcarbocyclic or heterocyclic ring; Z⁸ and Z⁹ are each independently C orN; Y¹ and Y² are each independently selected from the group consistingof a direct bond, O, and S; at least one of Y¹ and Y² is a direct bond;L¹ and L² are each independently selected from the group consisting of asingle bond, O, S, CR′R″, SiR′R″, BR′, and NR′, or is not present; atleast one of L¹ and L² is present; X¹ to X³ are each independently C orN; R^(D) and R^(E) each independently represents mono the maximumallowable substitution, or no substitution; each R′, R″, R^(C), andR^(D) is independently a hydrogen or a substituent selected from thegroup consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl,alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl,aryl, heteroaryl, nitrile, isonitrile, sulfanyl, boryl and combinationsthereof; and any two substituents may be joined or fused together toform a ring. 23.-31. (canceled)
 32. An organic light emitting device(OLED) comprising: an anode; a cathode; and an organic layer, disposedbetween the anode and the cathode, comprising a compound comprising afirst ligand L_(A) of Formula I

wherein, ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; wherein the first group isselected from the group consisting of:

wherein the asterisks in each structure indicate adjacent C atoms thatare on ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, boryl, and combinations thereof; the ligand L_(A) iscomplexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.
 33. (canceled)
 34. The OLED of claim 32, wherein theorganic layer further comprises a host, wherein host comprises at leastone chemical group selected from the group consisting of triphenylene,carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene,azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran,and aza-dibenzoselenophene.
 35. The OLED of claim 34, wherein the hostis selected from the group consisting of:

and combinations thereof.
 36. (canceled)
 37. A consumer productcomprising an organic light-emitting device (OLED) comprising: an anode;a cathode; and an organic layer, disposed between the anode and thecathode, comprising a compound comprising a first ligand L_(A) ofFormula I

wherein, ring A and ring B are each independently a 5-membered or6-membered carbocyclic or heterocyclic ring; Z¹ to Z⁵ are eachindependently C or N; two adjacent Z¹ to Z⁴ are not N; the Z¹ to Z⁴ thatconnects to ring B is C; R^(A), R^(B), and R^(C) each represents mono tothe maximum possible number of substitutions, or no substitution; twoadjacent R^(A) substituents, or two adjacent R^(C) substituents, form afirst group fused to ring A or ring C; wherein the first group isselected from the group consisting of:

wherein the asterisks in each structure indicate adjacent C atoms thatare on ring A or ring C; each R, R₁, R₂, R^(A), R^(B), and R^(C) isindependently a hydrogen or a substituent selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, boryl, and combinations thereof; the ligand L_(A) iscomplexed to a metal M to form a 5-membered chelate ring; the metal Mcan be coordinated to their ligands; the ligand L_(A) can be linked withother ligands to comprise a tridentate, tetradentate, pentadentate, orhexadentate ligand; and any two substituents can join or fuse togetherto form a ring.
 38. (canceled)
 39. A formulation comprising a compoundaccording to claim
 1. 40. (canceled)